SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric Chartography) is a spectrometer designed to measure sunlight transmitted, reflected, and scattered by the earth’s atmosphere or surface in the ultraviolet, visible, and near-infrared wavelength region (240–2380 nm) at moderate spectral resolution (0.2–1.5 nm, λ/Δλ ≈ 1000–10 000). SCIAMACHY will measure the earthshine radiance in limb and nadir viewing geometries and solar or lunar light transmitted through the atmosphere observed in occultation. The extraterrestrial solar irradiance and lunar radiance will be determined from observations of the sun and the moon above the atmosphere. The absorption, reflection, and scattering behavior of the atmosphere and the earth’s surface is determined from comparison of earthshine radiance and solar irradiance. Inversion of the ratio of earthshine radiance and solar irradiance yields information about the amounts and distribution of important atmospheric constituents and the spectral reflecta...

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SCIAMACHY: Mission Objectives and Measurement Modes

The quasi-biennial oscillation (QBO) dominates the variability of the equatorial stratosphere (∼16–50 km) and is easily seen as downward propagating easterly and westerly wind regimes, with a variable period averaging approximately 28 months. From a fluid dynamical perspective, the QBO is a fascinating example of a coherent, oscillating mean flow that is driven by propagating waves with periods unrelated to that of the resulting oscillation. Although the QBO is a tropical phenomenon, it affects the stratospheric flow from pole to pole by modulating the effects of extratropical waves. Indeed, study of the QBO is inseparable from the study of atmospheric wave motions that drive it and are modulated by it. The QBO affects variability in the mesosphere near 85 km by selectively filtering waves that propagate upward through the equatorial stratosphere, and may also affect the strength of Atlantic hurricanes. The effects of the QBO are not confined to atmospheric dynamics. Chemical constituents, such as ozone, water vapor, and methane, are affected by circulation changes induced by the QBO. There are also substantial QBO signals in many of the shorter-lived chemical constituents. Through modulation of extratropical wave propagation, the QBO has an effect on the breakdown of the wintertime stratospheric polar vortices and the severity of high-latitude ozone depletion. The polar vortex in the stratosphere affects surface weather patterns, providing a mechanism for the QBO to have an effect at the Earth's surface. As more data sources (e.g., wind and temperature measurements from both ground-based systems and satellites) become available, the effects of the QBO can be more precisely assessed. This review covers the current state of knowledge of the tropical QBO, its extratropical dynamical effects, chemical constituent transport, and effects of the QBO in the troposphere (∼0–16 km) and mesosphere (∼50–100 km). It is intended to provide a broad overview of the QBO and its effects to researchers outside the field, as well as a source of information and references for specialists. The history of research on the QBO is discussed only briefly, and the reader is referred to several historical review papers. The basic theory of the QBO is summarized, and tutorial references are provided.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/1999RG000073

The quasi-biennial oscillation

Stratospheric ozone depletion through cat- alytic chemistry involving man-made chlorofluorocar- bons is an area of focus in the study of geophysics and one of the global environmental issues of the twentieth century. This review presents a brief history of the sci- ence of ozone depletion and describes a conceptual framework to explain the key processes involved, with a focus on chemistry. Observations that may be considered as evidence (fingerprints) of ozone depletion due to chlorofluorocarbons are explored, and the related gas phase and surface chemistry is described. Observations of ozone and of chlorine-related trace gases near 40 km provide evidence that gas phase chemistry has indeed currently depleted about 10% of the stratospheric ozone there as predicted, and the vertical and horizontal struc- tures of this depletion are fingerprints for that process. More striking changes are observed each austral spring in Antarctica, where about half of the total ozone col- umn is depleted each September, forming the Antarctic ozone hole. Measurements of large amounts of ClO, a key ozone destruction catalyst, are among the finger- prints showing that human releases of chlorofluorocar- bons are the primary cause of this change. Enhanced ozone depletion in the Antarctic and Arctic regions is linked to heterogeneous chlorine chemistry that oc- curs on the surfaces of polar stratospheric clouds at cold temperatures. Observations also show that some of the same heterogeneous chemistry occurs on the surfaces of particles present at midlatitudes as well, and the abundances of these particles are enhanced following explosive volcanic eruptions. The partition- ing of chlorine between active forms that destroy ozone and inert reservoirs that sequester it is a central part of the framework for our understanding of the 40-km ozone decline, the Antarctic ozone hole, the recent Arctic ozone losses in particularly cold years, and the observation of record midlatitude ozone de- pletion after the major eruption of Mount Pinatubo in the early 1990s. As human use of chlorofluorocarbons continues to decrease, these changes throughout the ozone layer are expected to gradually reverse during the twenty-first century.

https://iri.columbia.edu/~goddard/EESC_W4400/CC/solomon_1999.pdf

Stratospheric ozone depletion: A review of concepts and history

We describe in this paper the modifications, improvements, and enhancements to the HITRAN molecular absorption database that have occurred in the two editions of 1991 and 1992 The current database includes line parameters for 31 species and their isotopomers that are significant for terrestrial atmospheric studies This line-by-line portion of HITRAN presently contains about 709,000 transitions between 0 and 23,000/cm and contains three molecules not present in earlier versions: COF2, SF6, and H2S The HITRAN compilation has substantially more information on chlorofluorocarbons and other molecular species that exhibit dense spectra which are not amenable to line-by-line representation The user access of the database has been advanced, and new media forms are now available for use on personal computers

The hitran molecular database: editions of 1991 and 1992

The Halogen Occultation Experiment (HALOE) uses solar occultation to measure vertical profiles of O3, HCl, HF, CH4, H2O, NO, NO2, aerosol extinction, and temperature versus pressure with an instantaneous vertical field of view of 1.6 km at the earth limb. Latitudinal coverage is from 80 deg S to 80 deg N over the course of 1 year and includes extensive observations of the Antarctic region during spring. The altitude range of the measurements extends from about 15 km to about 60-130 km, depending on channel. Experiment operations have been essentially flawless, and all performance criteria either meet or exceed specifications. Internal data consistency checks, comparisons with correlative measurements, and qualitative comparisons with 1985 atmospheric trace molecule spectroscopy (ATMOS) results are in good agreement. Examples of pressure versus latitude cross sections and a global orthographic projection for the September 21 to October 15, 1992, period show the utility of CH4, HF, and H2O as tracers, the occurrence of dehydration in the Antarctic lower stratosphere, the presence of the water vapor hygropause in the tropics, evidence of Antarctic air in the tropics, the influence of Hadley tropical upwelling, and the first global distribution of HCl, HF, and NO throughout the stratosphere. Nitric oxide measurements extend through the lower thermosphere.

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The Halogen Occultation Experiment

The Halogen Occultation Experiment (HALOE) on UARS uses the method of solar occultation limb sounding to measure the composition and structure of the stratosphere and mesosphere. One of the HALOE channels is spectrally centered at 3.4 μm to measure the vertical profile and global distribution of hydrogen chloride. The mean difference between HALOE and 14 balloon correlative underflight measurements ranges from 8% to 19% throughout most of the stratosphere. This difference is within the limits of error bar overlap for the two data sets. The mean differences between HALOE and HCl data from ATMOS flights on the space shuttle is of the order of 15 to 20% for the 1992 flight and 10% for the 1993 flight. Generally, HALOE results tend to be low in these comparisons. Also, comparisons with two-dimensional model calculations and HALOE data are in good qualitative agreement regarding vertical profile shapes and features in a pressure versus latitude cross section. HCl values increase from ∼0.3 parts per billion by volume (ppbv) to 1 ppbv in the lower stratosphere to 2.6 ppbv to 3.3 ppbv just above the stratopause which is the upper limit of HALOE single-profile measurements. There is a dependence of HCl results on the angle between the orbit plane and the Earth-Sun vector with HCl varying by ±9% in the upper stratosphere. This variation appears to be altitude dependent and it is not discernible in the data below about 10 mbar.

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Validation of hydrogen fluoride measurements made by the Halogen Occultation Experiment from the UARS platform

HALOE observations of O3, CH4, HF, H2O, NO, NO2, and HCl collected during the October 1991 Antarctic spring period are reported. The data show a constant CH4 mixing ratio of about 0.25 ppmv for the altitude range from 65 km down to about 25 km at the position of minimum wind speed in the vortex: i.e., the vortex center, and depressions in pressure versus longitude contours of NO, NO2, HF, and HCl in this same region. Water vapor, HF, and HCl enhancement are also observed in the vortex center region above about 25 km. Between 10 and 20 km, the expected mixing ratio signatures exist within the vortex, i.e., low ozone and dehydration. The water vapor increased by 50 percent, and the ozone level doubled inside the vortex between October 11 and 24 in the 15-20 km layer. These changes imply a time constant for recovery from ozone hole conditions of 19 and 30 days for O3 and H2O, respectively. The data further show the presence of air inside the vortex between 3 and 30 mb which has mixing ratios characteristic of midlatitudes.

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HALOE Antarctic observations in the Spring of 1991

The Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument recorded 19 sets of interferograms during solar occultations in both the Northern and Southern Hemispheres over the course of the Spacelab 3 mission. The resulting IR spectra furnish concentration profiles for over 25 atmospheric species. Attention is presently given to the volume mixing ratio profiles for HCl and HF in the 15-60-km altitude region, retrieved from northern sunsets and southern sunrises. The HF/HCl ratios deduced are in good agreement with model predictions. The total atmospheric chlorine at 50 km is nearly all in the form of HCl.

Infrared spectroscopic measurements of halogenated sink and reservoir gases in the stratosphere with the ATMOS instrument

The vertical mixing ratio profiles of H2O, HDO, O3, heavy ozone, HF, HCl, HCN, and OH in the stratosphere are retrieved from high-resolution far-infrared emission spectra. These spectra were obtained with a balloon-borne Fourier transform spectrometer in the spring of 1979 at 32 deg N. The nonlinear least squares fit method is used in the analysis. The results are obtained relative to the O2 mixing ratio, whose emission features can be found in the same spectra. The retrieval of OH together with other species should be particularly significant for the study of upper stratospheric photochemistry, although the errors are relatively large: 28 percent for OH and 16-19 percent for other species.

Jae H. Park

Papers

The Halogen Occultation Experiment

Validation of hydrogen fluoride measurements made by the Halogen Occultation Experiment from the UARS platform

HALOE Antarctic observations in the Spring of 1991

Infrared spectroscopic measurements of halogenated sink and reservoir gases in the stratosphere with the ATMOS instrument

Simultaneous measurement of minor stratospheric constituents with emission far-infrared spectroscopy