Showing papers by "Jan D'Haen published in 2020"

Inkjet Printing of PEDOT:PSS Based Conductive Patterns for 3D Forming Applications.

Abstract: This paper presents the formulation, inkjet printing, and vacuum forming of a conductive and stretchable polymer, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), ink on a stretchable and transparent thermoplastic polyurethane (TPU) substrate. The formulation of the conductive and stretchable ink is achieved by combining PEDOT:PSS with additional solvents, to achieve the right inkjet properties for drop-on-demand (DoD) inkjet printing. A conductive pattern can be printed from the 21 µm orifice on a flexible and stretchable TPU substrate, with a linewidth down to 44 µm. The properties of the printed pattern, in terms of sheet resistance, morphology, transparency, impact of weather conditions, and stretching are investigated and show sheet resistances up to 45 Ohm/sq and transparencies as high as 95%, which is comparable to indium tin oxide (ITO). Moreover, in contrast to ITO, one-time stretching up to 40% can be achieved, increasing the sheet resistance up to 214 Ohm/sq only, showing the great potential of this ink for one-time stretching. Finally, as a proof of this one-time stretching, the printed samples are vacuum formed around a 3D object, still showing sufficient conductivity to be applied as a capacitive touch sensor.

Phytostabilization of Polluted Military Soil Supported by Bioaugmentation with PGP-Trace Element Tolerant Bacteria Isolated from Helianthus petiolaris

Abstract: Lead (Pb) and cadmium (Cd) are major environmental pollutants, and the accumulation of these elements in soils and plants is of great concern in agricultural production due to their toxic effects on crop growth. Also, these elements can enter into the food chain and severely affect human and animal health. Bioaugmentation with plant growth-promoting bacteria (PGPB) can contribute to an environmentally friendly and effective remediation approach by improving plant survival and promoting element phytostabilization or extraction under such harsh conditions. We isolated and characterised Pb and Cd-tolerant root-associated bacteria from Helianthus petiolaris growing on a Pb/Cd polluted soil in order to compose inoculants that can promote plant growth and also ameliorate the phytostabilization or phytoextraction efficiency. One hundred and five trace element-tolerant rhizospheric and endophytic bacterial strains belonging to eight different genera were isolated from the aromatic plant species Helianthus petiolaris. Most of the strains showed multiple PGP-capabilities, ability to immobilise trace elements on their cell wall, and promotion of seed germination. Bacillus paramycoides ST9, Bacillus wiedmannii ST29, Bacillus proteolyticus ST89, Brevibacterium frigoritolerans ST30, Cellulosimicrobium cellulans ST54 and Methylobacterium sp. ST85 were selected to perform bioaugmentation assays in greenhouse microcosms. After 2 months, seedlings of sunflower (H. annuus) grown on polluted soil and inoculated with B. proteolyticus ST89 produced 40% more biomass compared to the non-inoculated control plants and accumulated 20 % less Pb and 40% less Cd in the aboveground plant parts. In contrast, B. paramycoides ST9 increased the bioaccumulation factor (BAF) of Pb three times and of Cd six times without inhibiting plant growth. Our results indicate that, depending on the strain, bioaugmentation with specific beneficial bacteria can improve plant growth and either reduce trace element mobility or enhance plant trace element uptake.

Constructive versus Destructive Heterogeneity in Porous Electrodes of Lithium-Ion Batteries

Abstract: We introduce an efficient framework for investigating the heterogeneity in battery porous electrodes and its impacts on the performance and longevity of lithium-ion batteries. A phenomenological pi...

2D layered perovskite containing functionalised benzothieno-benzothiophene molecules: formation, degradation, optical properties and photoconductivity

Abstract: 2D layered hybrid perovskites are currently in the spotlight for applications such as solar cells, light-emitting diodes, transistors and photodetectors. The structural freedom of 2D layered perovskites allows for the incorporation of organic cations that can potentially possess properties contributing to the performance of the hybrid as a whole. In this study, we incorporated a benzothieno[3,2-b]benzothiophene (BTBT) alkylammonium cation into the organic layer of a 2D layered lead iodide perovskite. The formation and degradation of this material are discussed in detail. It is shown that the use of a solvent vapour annealing method significantly enhances the absorption, emission and crystallinity of films of this 2D layered perovskite as compared to regular thermal annealing. The photoconductivity of the films was determined using time-resolved microwave conductivity (TRMC) as well as in a device. In both cases, the solvent vapour annealed films show markedly higher photoconductivity than the films obtained using the regular thermal annealing approach.

Layer Morphology and Ink Compatibility of Silver Nanoparticle Inkjet Inks for Near-Infrared Sintering.

Abstract: The field of printed electronics is rapidly evolving, producing low cost applications with enhanced performances with transparent, stretchable properties and higher reliability. Due to the versatility of printed electronics, industry can consider the implementation of electronics in a way which was never possible before. However, a post-processing step to achieve conductive structures-known as sintering-limits the production ease and speed of printed electronics. This study addresses the issues related to fast sintering without scarifying important properties such as conductivity and surface roughness. A drop-on-demand inkjet printer is employed to deposit silver nanoparticle-based inks. The post-processing time of these inks is reduced by replacing the conventional oven sintering procedure with the state-of-the-art method, named near-infrared sintering. By doing so, the post-processing time shortens from 30-60 min to 6-8 s. Furthermore, the maximum substrate temperature during sintering is reduced from 200 °C to 120 °C. Based on the results of this study, one can conclude that near-infrared sintering is a ready-to-industrialize post-processing method for the production of printed electronics, capable of sintering inks at high speed, low temperature and with low complexity. Furthermore, it becomes clear that ink optimization plays an important role in processing inkjet printable inks, especially after being near-infrared sintered.

Thermo-Mechanical Stress Comparison of a GaN and SiC MOSFET for Photovoltaic Applications

Abstract: Integrating photovoltaic applications within urban environments creates the need for more compact and efficient power electronics that can guarantee long lifetimes. The upcoming wide-bandgap semiconductor devices show great promise in providing the first two properties, but their packaging requires further testing in order to optimize their reliability. This paper demonstrates one iteration of the design for reliability methodology used in order to compare the generated thermo-mechanical stress in the die attach and the bond wires of a GaN and SiC MOSFET. An electro-thermal model of a photovoltaic string inverter is used in order to translate a cloudy and a clear one-hour mission profile from Arizona into a junction losses profile. Subsequently, the finite element method models of both devices are constructed through reverse engineering in order to analyze the plastic energy. The results show that the plastic energy in the die attach caused by a cloudy mission-profile is much higher than that caused by a clear mission-profile. The GaN MOSFET, in spite of its reduced losses, endures around 5 times more plastic energy dissipation density in its die attach than the SiC MOSFET while the reverse is true for the bond wires. Potential design adaptations for both devices have been suggested to initiate a new iteration in the design for reliability methodology, which will ultimately lead to a more reliable design.

Cable Bacteria as Long-Range Biological Semiconductors

Abstract: Filamentous cable bacteria exhibit unprecedented long-range biological electron transport, which takes place in a parallel fibre structure that shows an extraordinary electrical conductivity for a biological material. Still, the underlying electron transport mechanism remains undisclosed. Here we determine the intrinsic electrical properties of individual cable bacterium filaments. We retrieve an equivalent electrical circuit model, characterising cable bacteria as resistive biological wires. Temperature dependent experiments reveal that the charge transport is thermally activated, and can be described with an Arrhenius-type relation over a broad temperature range (-196°C to +50°C), thus excluding metal-like electron transport. Furthermore, when cable bacterium filaments are utilized as the channel in a field-effect transistor, they show n-type transport, indicating that electrons rather than holes are the charge carriers. Electron mobilities are in the order of 10-1 cm²/Vs, comparable to many organic semiconductors. This new type of biological centimetre-range semiconductor with low resistivity offers new perspectives for both fundamental studies and applications in (bio)electronics.

Phase Behavior in the Active Layer of Small Molecule Organic Photovoltaics: State Diagram of p-DTS(FBTTh₂)₂:PC₇₁BM

Abstract: A comprehensive study was undertaken to obtain a more fundamental understanding of the phase behavior of the p-DTS(FBTTh₂)₂:PC₇₁BM system, used in small molecule organic solar cells, with a strong focus on the amorphous phase and its influence on crystallinity. Three dedicated thermal protocols were used in combination with advanced thermal analysis, solid-state NMR, and wide-angle X-ray diffraction. Rapid cooling, to avoid structure formation and gain insight in the amorphous phase, and slow cooling, to promote structure formation, were used as limiting cases to explain the intermediate behavior after device processing from solution. A complete state diagram was developed, and the glass transition (Tg)–composition relationship was determined. In the case of slow cooling and the procedure used for device processing, the rapid crystallization of p-DTS(FBTTh₂)₂ leads to an enrichment of the amorphous phase in PC₇₁BM, increasing its Tg and causing vitrification of the mixed amorphous phase before crystallization when the total amount of PC₇₁BM exceeds 70 wt %. The common processing additive 1,8-diiodooctane (DIO) was found to lead to a lower p-DTS(FBTTh₂)₂ crystallinity and smaller average crystal size. More importantly, it acts as a strong plasticizer, lowering Tg significantly and thus reducing the morphological stability of the p-DTS(FBTTh₂)₂:PC₇₁BM mixtures.

Phase Behavior in the Active Layer of Small Molecule Organic Photovoltaics: State Diagram of p-DTS(FBTTh2)2:PC71BM

Abstract: A comprehensive study was undertaken to obtain a more fundamental understanding of the phase behavior of the p-DTS(FBTTh2)2:PC71BM system, used in small molecule organic solar cells, with a strong ...