Metamaterials are typically engineered by arranging a set of small scatterers or apertures in a regular array throughout a region of space, thus obtaining some desirable bulk electromagnetic behavior. The desired property is often one that is not normally found naturally (negative refractive index, near-zero index, etc.). Over the past ten years, metamaterials have moved from being simply a theoretical concept to a field with developed and marketed applications. Three-dimensional metamaterials can be extended by arranging electrically small scatterers or holes into a two-dimensional pattern at a surface or interface. This surface version of a metamaterial has been given the name metasurface (the term metafilm has also been employed for certain structures). For many applications, metasurfaces can be used in place of metamaterials. Metasurfaces have the advantage of taking up less physical space than do full three-dimensional metamaterial structures; consequently, metasurfaces offer the possibility of less-lossy structures. In this overview paper, we discuss the theoretical basis by which metasurfaces should be characterized, and discuss their various applications. We will see how metasurfaces are distinguished from conventional frequency-selective surfaces. Metasurfaces have a wide range of potential applications in electromagnetics (ranging from low microwave to optical frequencies), including: (1) controllable “smart” surfaces, (2) miniaturized cavity resonators, (3) novel wave-guiding structures, (4) angular-independent surfaces, (5) absorbers, (6) biomedical devices, (7) terahertz switches, and (8) fluid-tunable frequency-agile materials, to name only a few. In this review, we will see that the development in recent years of such materials and/or surfaces is bringing us closer to realizing the exciting speculations made over one hundred years ago by the work of Lamb, Schuster, and Pocklington, and later by Mandel'shtam and Veselago.

An Overview of the Theory and Applications of Metasurfaces: The Two-Dimensional Equivalents of Metamaterials

Six years after their birth, terahertz quantum-cascade lasers can now deliver milliwatts or more of continuous-wave coherent radiation throughout the terahertz range — the spectral regime between millimetre and infrared wavelengths, which has long resisted development. This paper reviews the state-of-the-art and future prospects for these lasers, including efforts to increase their operating temperatures, deliver higher output powers and emit longer wavelengths.

Terahertz quantum-cascade lasers

Nature routinely produces nanostructured surfaces with useful properties, such as the self-cleaning lotus leaf, the colour of the butterfly wing, the photoreceptor in brittlestar and the anti-reflection observed in the moth eye. Scientists and engineers have been able to mimic some of these natural structures in the laboratory and in real-world applications. Here, we report a simple aperiodic array of silicon nanotips on a 6-inch wafer with a sub-wavelength structure that can suppress the reflection of light at a range of wavelengths from the ultraviolet, through the visible part of the spectrum, to the terahertz region. Reflection is suppressed for a wide range of angles of incidence and for both s- and p-polarized light. The antireflection properties of the silicon result from changes in the refractive index caused by variations in the height of the silicon nanotips, and can be simulated with models that have been used to explain the low reflection from moth eyes. The improved anti-reflection properties of the surfaces could have applications in renewable energy and electro-optical devices for the military.

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Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures

Within the last several years, the field of terahertz science and technology has changed dramatically. Many new advances in the technology for generation, manipulation, and detection of terahertz radiation have revolutionized the field. Much of this interest has been inspired by the promise of valuable new applications for terahertz imaging and sensing. Among a long list of proposed uses, one finds compelling needs such as security screening and quality control, as well as whimsical notions such as counting the almonds in a bar of chocolate. This list has grown in parallel with the development of new technologies and new paradigms for imaging and sensing. Many of these proposed applications exploit the unique capabilities of terahertz radiation to penetrate common packaging materials and provide spectroscopic information about the materials within. Several of the techniques used for terahertz imaging have been borrowed from other, more well established fields such as x-ray computed tomography and synthetic aperture radar. Others have been developed exclusively for the terahertz field, and have no analogies in other portions of the spectrum. This review provides a comprehensive description of the various techniques which have been employed for terahertz image formation, as well as discussing numerous examples which illustrate the many exciting potential uses for these emerging technologies.

https://iopscience.iop.org/article/10.1088/0034-4885/70/8/R02/pdf

Imaging with terahertz radiation

Introductory Fourier transform spectroscopy

A method for reducing the reflections from silicon optics at terahertz frequencies has been investigated. In this study, we used thin films of parylene as an anti-reflection (AR) layer for silicon optics and show low-loss behavior well above 1 THz. Transmittance spectra are acquired on double-sided-parylene-coated, high-resistivity, single-crystal silicon etalons between 0.45 THz and 2.8 THz. Modeling the optical behavior of the three-layer system allowed for the determination of the refractive index and absorption coefficient of parylene at these frequencies. Our data indicate a refractive index, n, of 1.62 for parylene C and parylene D, and a reasonably modest absorption coefficient make these materials a suitable AR coating for silicon at terahertz frequencies. Coatings sufficiently thick for AR performance reduced the average transmittance of the three-layer system by <10% compared to a lossless AR coating with an ideal refractive index.

An anti-reflection coating for silicon optics at terahertz frequencies

A high resolution submillimeter interferometer system for measurement of electron densities in the 1014-cm−3 ≤ ne ≤ 2 × 1015-cm−3 range has been developed for use in high density tokamaks. Phase modulation at ~1 MHz is accomplished by difference frequency mixing of two cavity tuned laser oscillators. The optically pumped CH3OH lasers, which operate on the 118.8-μm line, feature a novel output coupling design that permits good mode quality and low beam divergence. The beat signals are detected using a newly developed Ge:Li photoconductor, and a direct measurement of the phase shift is obtained from the time lag between probe and reference signals. The sensitivity of the resulting phase measurement is independent of the instantaneous phase and unaffected by fluctuations in the amplitude or in the frequency of the modulation.

Modulated submillimeter laser interferometer system for plasma density measurements.

In response to the growing interest in developing terahertz imaging systems for concealed weapons detection, the Submillimeter-Wave Technology Laboratory (STL) at the University of Massachusetts Lowell has produced full-body terahertz imagery using coherent active radar measurement techniques. The proof-of-principle results were readily obtained utilizing the compact radar range resources at STL. Two contrasting techniques were used to collect the imagery. Both methods made use of in-house transceivers, consisting of two ultra-stable far-infrared lasers, terahertz heterodyne detection systems, and terahertz anechoic chambers. The first technique involved full beam subject illumination with precision azimuth and elevation control to produce high resolution images via two axis Fourier transforms. Imagery collected in this manner is presented at 1.56THz and 350GHz. The second method utilized a focused spot, moved across the target subject in a high speed two dimensional raster pattern created by a large two-axis positioning mirror. The existing 1.56THz compact radar range was modified to project a focused illumination spot on the target subject several meters away, and receive the back-reflected intensity. The process was repeated across two dimensions, and the resultant image was assembled and displayed utilizing minimal on-the-fly processing. Imagery at 1.56THz of human subjects with concealed weapons are presented and discussed for this scan type.

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Terahertz imaging of subjects with concealed weapons

Submillimeter lasers optically pumped off resonance

A coherent transceiver using a THz quantum cascade (TQCL) laser as the transmitter and an optically pumped molecular laser as the local oscillator has been used, with a pair of Schottky diode mixers in the receiver and reference channels, to acquire high-resolution images of fully illuminated targets, including scale models and concealed objects. Phase stability of the received signal, sufficient to allow coherent image processing of the rotating target (in azimuth and elevation), was obtained by frequency-locking the TQCL to the free-running, highly stable optically pumped molecular laser. While the range to the target was limited by the available TQCL power (several hundred microwatts) and reasonably strong indoor atmospheric attenuation at 2.408 THz, the coherence length of the TQCL transmitter will allow coherent imaging over distances up to several hundred meters. Image data obtained with the system is presented.

https://apps.dtic.mil/dtic/tr/fulltext/u2/a528772.pdf

Jerry Waldman

Papers

An anti-reflection coating for silicon optics at terahertz frequencies

Modulated submillimeter laser interferometer system for plasma density measurements.

Terahertz imaging of subjects with concealed weapons

Submillimeter lasers optically pumped off resonance

Terahertz inverse synthetic aperture radar (ISAR) imaging with a quantum cascade laser transmitter.