J
Jian-Rong Gao
Researcher at Zhejiang University of Technology
Publications - 105
Citations - 1881
Jian-Rong Gao is an academic researcher from Zhejiang University of Technology. The author has contributed to research in topics: Cycloaddition & Catalysis. The author has an hindex of 23, co-authored 105 publications receiving 1561 citations. Previous affiliations of Jian-Rong Gao include Zhejiang University.
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Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions
TL;DR: A highly enantioselective intramolecular arylative dearomatization of indoles via palladium-catalyzed reductive Heck reactions was developed and led to a series of optically active indolines bearing C2-quaternary stereocenters in modest to good yields with excellent enantiOSElectivities.
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Palladium/l-Proline-Catalyzed Enantioselective α-Arylative Desymmetrization of Cyclohexanones
TL;DR: A highly enantioselective palladium/l-proline-catalyzed α-arylative desymmetrization of cyclohexanones was developed and led to a series of optically active morphan derivatives bearing α-carbonyl tertiary stereocenters in good yields with excellent enantiOSElectivities.
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Indolizine Synthesis via Oxidative Cross-Coupling/Cyclization of Alkenes and 2-(Pyridin-2-yl)acetate Derivatives.
TL;DR: A novel copper/I2-mediated oxidative cross-coupling/cyclization of 2-(pyridin-2-yl)acetate derivatives and simple olefins is developed, which provides a straightforward and efficient access to structural diversely indolizines.
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Iodine-Promoted Construction of Polysubstituted 2,3-Dihydropyrroles from Chalcones and β-Enamine Ketones (Esters).
TL;DR: A novel approach for the synthesis of a variety of polysubstituted trans-2,3-dihydropyrroles from a wide range of chalcones and β-enamine ketones via iodine-promoted tandem Michael/cyclization sequence has been developed, affording the desired products in moderate to excellent yields.
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Iodine-Catalyzed 1,3-Dipolar Cycloaddition/Oxidation/Aromatization Cascade with Hydrogen Peroxide as the Terminal Oxidant: General Route to Pyrrolo[2,1-a]isoquinolines
TL;DR: A novel molecular iodine-catalyzed 1,3-dipolar cycloaddition/oxidation/aromatization cascade process with hydrogen peroxide as the terminal oxidant for the construction of pyrrolo[2,1-a]isoquinolines is reported.