Jie Song

TL;DR: This review addresses central issues in green energy generation, the challenges in water oxidation catalyst development, and the possible uses of polyoxometalates in greenEnergy science.

TL;DR: A combination of polyanion size and charge allows the Keggin-type polyoxometalate (POM), a catalyst for some air-based organic oxidations, to fit snuggly in the pores of MOF-199 (HKUST-1), a metal-organic framework (MOF) with the POM countercations residing in alternative pores results in a substantial synergistic stabilization of both the MOF and the Pom.

TL;DR: The photocatalytic performance of this catalyst is superior to that of the previously reported precious-metal-based polyoxometalate water oxidation catalyst.

TL;DR: Multiple experimental results confirm that the polyanion unit (1-V2) itself is the dominant active catalyst and not Co(2+)(aq) or cobalt oxide.

TL;DR: Two inorganic-organic hybrid clusters synthesized from Lindqvist type polyoxometalates results in amphiphilic hybrid molecules and simultaneously offers a great opportunity to study the interaction between hybrid clusters and their counterions.