Jingui Duan

TL;DR: An rht-type metal-organic framework prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylates ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(1)/N(2).

TL;DR: The structural change by photochemical transformation of this PCP via [2 + 2] photodimerization leads to the removal of inverse CO2/C2H2 selectivity, verifying the mechanism of the guest discriminatory gate effect.

TL;DR: In this paper, a review of water-resistant porous coordination polymers is presented with an emphasis on their adsorptive-and membrane-based gas separations, which is intended to be useful for researchers who are interested in designing water resistant PCPs and exploring promising applications for gas separation.

TL;DR: 2-Ln MOFs realize nearly white light emission by means of a trichromatic approach and exhibit water stability and demonstrate high selective and sensitive sensing activities toward Fe(III) and Cr(VI) in aqueous solutions, highlighting the importance of the ligand flexibility on tuning MOF structures with improved structural stability and ion-sensing properties.

TL;DR: In this article, a new PCP called [La(BTN)DMF]·guest (PCP-1⊃guest), which has a large aromatic organic surface and a low binding energy for high CO2 separation from four-gas mixtures (CO2-N2-O2-CO) at ambient temperature, was proposed.