Journal ArticleDOI
Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal-Organic Framework Decorated with Acylamide Groups
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TLDR
An rht-type metal-organic framework prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylates ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(1)/N(2).Abstract:
An rht-type metal−organic framework (MOF) prepared from M2(carboxylate)4 (M = Cu, Co) paddlewheel clusters and a flexible C3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N2 in comparison with what was previously observed for an analogous MOF with alkyne groups.read more
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI
Metal–Organic Frameworks for Separations
Journal ArticleDOI
Carbon Dioxide Capture in Metal–Organic Frameworks
Kenji Sumida,David L. Rogow,Jarad A. Mason,Thomas M. McDonald,Eric D. Bloch,Zoey R. Herm,Tae-Hyun Bae,Jeffrey R. Long +7 more
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
Journal ArticleDOI
Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
Jian-Rong Li,Yuguang Ma,M. Colin McCarthy,Julian P. Sculley,Jiamei Yu,Hae-Kwon Jeong,Perla B. Balbuena,Hong-Cai Zhou +7 more
TL;DR: In this article, the authors review the research progress in metal-organic frameworks (MOFs) for CO 2 adsorption, storage, and separations that are directly related to CO 2 capture.
Journal ArticleDOI
Tuning the structure and function of metal–organic frameworks via linker design
Weigang Lu,Zhangwen Wei,Zhi-Yuan Gu,Tian-Fu Liu,Jinhee Park,Jihye Park,Jian Tian,Muwei Zhang,Qiang Zhang,Thomas Gentle,Mathieu Bosch,Hong-Cai Zhou +11 more
TL;DR: This critical review of metal-organic frameworks (MOFs) highlights advances in MOF synthesis focusing on linker design and examples of building MOFs to reach unique properties, such as unprecedented surface area, pore aperture, molecular recognition, stability, and catalysis, through linkers are described.
References
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Journal ArticleDOI
Carbon Dioxide Capture: Prospects for New Materials
TL;DR: The most recent developments and emerging concepts in CO(2) separations by solvent absorption, chemical and physical adsorption, and membranes, amongst others, will be discussed, with particular attention on progress in the burgeoning field of metal-organic frameworks.
Journal ArticleDOI
Ultrahigh Porosity in Metal-Organic Frameworks
Hiroyasu Furukawa,Nakeun Ko,Yong Bok Go,Naoki Aratani,Sang Beom Choi,Eunwoo Choi,A. Oezguer Yazaydin,Randall Q. Snurr,Michael O'Keeffe,Jaheon Kim,Omar M. Yaghi +10 more
TL;DR: The synthesis of a MOF in which zinc centers are bridged with long, highly conjugated organic linkers, but in which the overall symmetry of the networks created prevents formation of interpenetrating networks is described.
Journal ArticleDOI
Thermodynamics of mixed‐gas adsorption
Alan L. Myers,John M. Prausnitz +1 more
TL;DR: In this paper, a simple technique is described for calculating the adsorption equilibria for components in a gaseous mixture, using only data for the pure-component adaption equilibrium at the same temperature and on the same adsorbent.
PatentDOI
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature
Omar M. Yaghi,Andrew R. Millward +1 more
TL;DR: A carbon dioxide storage system includes a container and a conduit attached to the container for introducing or removing a carbon dioxide-containing composition from the container as mentioned in this paper, which is positioned within the container.
Journal ArticleDOI
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
Hiroyasu Furukawa,Omar M. Yaghi +1 more
TL;DR: Findings place COFs among the most porous and the best adsorbents for hydrogen, methane, and carbon dioxide.