Jonas C. Peters

TL;DR: A combined synthetic, structural, and spectroscopic/analytic study to estimate the N-H bond strengths of several species of interest and provides insight into the facile reactivity profiles of early stage protonated Fe-N2 and Fe-CN species.

TL;DR: Electrochemical studies are discussed that help to contextualize the BQA ligand with respect to its neutral counterpart 2,2',2''-terpyridine (terpy) in terms of electron-releasing character.

TL;DR: In this article, a group 3 metal complex with tridentate phosphido-diphosphine ligands was synthesized for ring opening polymerization of lactide, which exhibited high activity and good polymerization control, shown by linear fits in the plot of number-averaged molecular weight (Mn) versus the percentage conversion and versus the monomer/initiator ratio.

TL;DR: This study lends strong support to the assignment that the molybdenum-iron cofactor of nitrogenase contains two [Fe-H(-)-Fe] bridging-hydride fragments in the catalytic intermediate that has accumulated four reducing equivalents (E(4).

TL;DR: The synthesis and characterization of a thiolate-coordinated FeIII(H)(N2) complex, which releases H2 upon warming to yield an FeII-N2-FeII complex is reported.