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Jonas C. Peters

Researcher at California Institute of Technology

Publications -  232
Citations -  28779

Jonas C. Peters is an academic researcher from California Institute of Technology. The author has contributed to research in topics: Catalysis & Ligand. The author has an hindex of 79, co-authored 231 publications receiving 23468 citations. Previous affiliations of Jonas C. Peters include Massachusetts Institute of Technology.

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Mid- to high-valent imido and nitrido complexes of iron

TL;DR: This short review summarizes recent advances in the synthesis and reactivity of iron imides and nitrides, and monometallic and multimetallic assemblies featuring these moieties are discussed.
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Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes.

TL;DR: The CAAC family of carbene ligands are demonstrated to have utility in affording access to the first examples of two-coordinate formal Fe(0) and Co( 0) [(CAAC)2M] complexes, prepared by reduction of their corresponding two- coordinate cationic Fe(I) andcoffee precursors.
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Zwitterionic and cationic bis(phosphine) platinum(II) complexes: structural, electronic, and mechanistic comparisons relevant to ligand exchange and benzene C-H activation processes.

TL;DR: Examination of the kinetics of the THF exchange process in benzene shows that neutral 13 reacts faster than both of the cations 14 and 15, and the magnitude of the primary kinetic isotope effect measured for the neutral versus the cationic systems differs markedly.
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Nitrogen Fixation via a Terminal Fe(IV) Nitride.

TL;DR: It is shown that a nitrogen-fixing Fe-N2 catalyst can be protonated to form a neutral Fe(NNH2) hydrazido(2-) intermediate, which, upon further protonation, heterolytically cleaves the N-N bond to release [FeIV≡N]+ and NH3 and provides direct evidence for the viability of a Chatt-type (distal) mechanism for Fe-mediated N2-to-NH3 conversion.