Joshua D. Howe

TL;DR: In this paper, an analysis of the CO2 adsorption properties of a well-known series of metal-organic frameworks M2(dobdc) is carried out in tandem with in situ structural studies to identify the host-guest interactions that lead to significant differences in isosteric heats of CO2 adducts.

TL;DR: In this article, the binding enthalpies of 14 different small molecules in a series of isostructural metal-organic frameworks, M-MOF-74, with M = Mg, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn.

TL;DR: The reversible CO binding suggests that these frameworks may be of utility for the separation of CO from various industrial gas mixtures, including CO/H2 and CO/N2, and selectivities determined from gas adsorption isotherm data using ideal adsorbed solution theory (IAST) indicate that all six M2(dobdc) frameworks could potentially be used as solid adsorbents to replace current cryogenic distillation technologies.

TL;DR: In this article, an ion-sieving carbon nanoshell coated ZnO nanoparticle anode is reported, synthesized in a scalable way with controllable shell thickness, to solve the problems of passivation and dissolution simultaneously.

TL;DR: In this paper, the reproducibility of CO2 adsorption in metal-organic framework (MOF) materials is evaluated via a retrospective analysis of reported data, showing that only 15 of the thousands of known MOFs for which enough experiments have been reported to allow strong conclusions to be drawn.