József Madarász

TL;DR: A green process for enantioselective hydrogenation of dehydroamino acid derivatives and dimethyl itaconate with a rhodium catalyst modified by a new phosphine-phosphoramidite has been developed as mentioned in this paper.

TL;DR: In this paper, the authors evaluated the feasibility of the above-mentioned bioconversion in solvent-free media, considered as a cleaner way ahead, and the successful applicability of miniaturized, continuous flow reactors for the biocatalytic reaction was demonstrated since isoamyl oleate could be obtained as long as 144h in the H-Cube™ without any significant loss of enzyme activity.

TL;DR: In this paper, a continuous flow reaction system using a stationary-phase catalyst for asymmetric hydrogenation of methyl acetamidoacrylate was developed and run continuously for 12 h with >99% conversion and 96-97% enantioselectivity.

TL;DR: In this article, a homochiral diphosphine with C 1 -symmetry from the cyclic sulfate of (2 R, 4 R )-2,4-pentanediol is reported.

TL;DR: A series of new phosphine-phosphite ligands P(C)(n)OP have been synthesized and used for rhodium-catalyzed asymmetric hydrogenation of prochiral olefins in order to study the effect of the chelate ring size.