다중혈관 관상동맥 환자에서 y-문합을 이용하여 양쪽 내흉동맥만을 사용한 우회술의 조기 성적

Highly porous nanocellulose aerogels can be prepared by vacuum freeze-drying from microfibrillated cellulose hydrogels. Here we show that by functionalizing the native cellulose nanofibrils of the aerogel with a hydrophobic but oleophilic coating, such as titanium dioxide, a selectively oil-absorbing material capable of floating on water is achieved. Because of the low density and the ability to absorb nonpolar liquids and oils up to nearly all of its initial volume, the surface modified aerogels allow to collect organic contaminants from the water surface. The materials can be reused after washing, recycled, or incinerated with the absorbed oil. The cellulose is renewable and titanium dioxide is not environmentally hazardous, thus promoting potential in environmental applications.

Hydrophobic nanocellulose aerogels as floating, sustainable, reusable, and recyclable oil absorbents.

Silica aerogels have drawn a lot of interest both in science and technology because of their low bulk density (up to 95% of their volume is air), hydrophobicity, low thermal conductivity, high surface area, and optical transparency. Aerogels are synthesized from molecular precursors by sol-gel processing. Special drying techniques must be applied to replace the pore liquid with air while maintaining the solid network. Supercritical drying is most common; however, recently developed methods allow removal of the liquid at atmospheric pressure after chemical modification of the inner surface of the gels, leaving only a porous silica network filled with air. Therefore, by considering the surprising properties of aerogels, the present review addresses synthesis of silica aerogels by the sol-gel method, as well as drying techniques and applications in current industrial development and scientific research.

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Silica aerogel: synthesis and applications

Aerogel is a kind of synthetic porous material, in which the liquid component of the gel is replaced with a gas. Aerogel has specific acoustic properties and remarkably lower thermal conductivity (≈0.013 W/m K) than the other commercial insulating materials. It also has superior physical and chemical characteristics like the translucent structure. Therefore, it is considered as one of the most promising thermal insulating materials for building applications. Besides its applications in residential and industrial buildings, aerogel has a great deal of application areas such as spacecrafts, skyscrapers, automobiles, electronic devices, clothing etc. Although current cost of aerogel still remains higher compared to the conventional insulation materials, intensive efforts are made to reduce its manufacturing cost and hence enable it to become widespread all over the world. In this study, a comprehensive review on aerogel and its utilization in buildings are presented. Thermal insulation materials based on aerogel are illustrated with various applications. Economic analysis and future potential of aerogel are also considered in the study.

Toward aerogel based thermal superinsulation in buildings: A comprehensive review

Silica aerogels are lightweight and highly porous materials, with a three-dimensional network of silica particles, which are obtained by extracting the liquid phase of silica gels under supercritical conditions. Due to their outstanding characteristics, such as extremely low thermal conductivity, low density, high porosity and high specific surface area, they have found excellent potential application for thermal insulation systems in aeronautical/aerospace and earthly domains, for environment clean up and protection, heat storage devices, transparent windows systems, thickening agents in paints, etc. However, native silica aerogels are fragile and sensitive at relatively low stresses, which limit their application. More durable aerogels, with higher strength and stiffness, can be obtained by proper selection of the silane precursors, and constructing the silica inorganic networks by compounding them with different organic polymers or different fiber networks. Recent studies showed that adding flexible organic polymers to the hydroxyl groups on the silica gel surface would be an effective mechanical reinforcing method of silica aerogels. More versatile polymer reinforcement approach can be readily achieved if proper functional groups are introduced on the surface of silica aerogels and then co-polymerized with appropriate organic monomers. The mechanical reinforced silica aerogels, with their very open texture, can be an outstanding thermal insulator material for different industrial and aerospace applications.

This paper presents a review of the literature on the methods for mechanical reinforcing of silica aerogels and discusses the recent achievements in improving the strength and elastic response of native silica aerogels along with cost effectiveness of each methodology.

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An overview on silica aerogels synthesis and different mechanical reinforcing strategies

The experimental work has been carried out to study the absorption–desorption properties of the hydrophobic silica aerogel for the application of oil spill cleanup. Aerogels were synthesized by sol–gel route prior to ambient pressure drying, by keeping TEOS:MeOH:Acidic H2O:NH4F:NH4OH:HMDZ molar ratio constant at 1:16.5:0.81:0.62:0.63:0.41, respectively. The absorption of organic liquids by as-prepared aerogels has been carried out by adding the aerogel samples in organic liquid, viz. three alkanes: hexane, heptane, octane; the aromatic compounds: benzene, toluene, xylene; the alcohols: methanol, ethanol, propanol, and the three oils: petrol, diesel, and kerosene until it is totally wetted. It was observed that surface-modified TEOS-based aerogel absorbed the organic liquids and oils by nearly 12 times its own mass. After absorption, desorption time of liquids from the aerogel at various temperatures, i.e., at 30, 60, 80, and 100 °C was measured. The 50% volume shrinkage of the aerogel in case of oils and 20% in case of organic liquid was observed, after total desorption of liquids. No significant change in hydrophobicity of the aerogel was observed and it can be reused two times.

Jyoti L. Gurav

Papers

Silica aerogel: synthesis and applications

Ambient pressure dried TEOS-based silica aerogels: good absorbents of organic liquids

Physical properties of sodium silicate based silica aerogels prepared by single step sol–gel process dried at ambient pressure

Synthesis of glycine combusted NiFe2O4 spinel ferrite: A highly versatile gas sensor

Superhydrophobic silica coating by dip coating method