K
Konstantin V. Bukhryakov
Researcher at Massachusetts Institute of Technology
Publications - 36
Citations - 552
Konstantin V. Bukhryakov is an academic researcher from Massachusetts Institute of Technology. The author has contributed to research in topics: Catalysis & Metathesis. The author has an hindex of 13, co-authored 32 publications receiving 474 citations. Previous affiliations of Konstantin V. Bukhryakov include King Abdullah University of Science and Technology & Moscow State University.
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Surface-Bound Ligands Modulate Chemoselectivity and Activity of a Bimetallic Nanoparticle Catalyst
TL;DR: In this paper, a bimetallic (PtFe) NP catalyst was shown to be remarkably competent in catalyzing the hydrogenation of cinnamaldehyde; NPs stabilized by hydrocarbon ligands were significantly less active.
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Imidazo[1,2-a]quinoxalines accessed via two sequential isocyanide-based multicomponent reactions.
TL;DR: A novel synthetic protocol toward imidazo[1,2-a]quinoxalines has been developed that includes two isocyanide-based multicomponent reactions sequentially introducing four diversity elements to the final products.
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Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene.
Jonathan K. Lam,Congqing Zhu,Konstantin V. Bukhryakov,Peter Müller,Amir H. Hoveyda,Richard R. Schrock +5 more
TL;DR: Methods of synthesizing new potential catalysts in which M = Mo or W, NR = N-2,6-diisopropylphenyl or NC6F5, and L is a phosphine, a pyridine, or a nitrile are reported, which indicate that tungsten complexes are inactive in the test reaction either because the donor is bound too strongly or because acetonitrile inserts into a W═C bond.
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Enzyme-Inspired Functional Surfactant for Aerobic Oxidation of Activated Alcohols to Aldehydes in Water
TL;DR: An enzyme-inspired catalytic system based on a rationally designed multifunctional amphiphile that effect chemoselective aerobic alcohol oxidation under ambient conditions in water, a transformation that is challenging to achieve nonenzymatically.
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Syntheses of Molybdenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex
TL;DR: Compound 6 in the presence of B(C6F5)3 will initiate the ring-opening metathesis polymerization of cyclooctene, 5,6-dicarbomethoxynorbornadiene (DCMNBD), and rac-5, 6-dimethoxyethane ( DCMNBE), and the homocoupling of 1-decene to 9-octadecene.