L
Luciano Forlani
Researcher at University of Bologna
Publications - 93
Citations - 972
Luciano Forlani is an academic researcher from University of Bologna. The author has contributed to research in topics: Nucleophile & Electrophilic aromatic substitution. The author has an hindex of 17, co-authored 93 publications receiving 922 citations.
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Journal ArticleDOI
Reinvestigation of the tautomerism of some substituted 2-hydroxypyridines
Luciano Forlani,Giampiero Cristoni,Carla Boga,Paolo E. Todesco,Erminia Del Vecchio,Simona Selva,Magda Monari +6 more
TL;DR: In this paper, the tautomerism of substituted 2-hydroxypyridines is investigated by UV/Vis- and 1 H-, and 13 C- NMR spectroscopic methods, with the aid of the N-Me and O-Me fixed parents.
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Evidence for Carbon–Carbon Meisenheimer–Wheland Complexes between Superelectrophilic and Supernucleophilic Carbon Reagents
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Condensation of thiourea derivatives with carbonyl compounds: one-pot synthesis of N-alkyl-1,3-thiazol-2-amines and of 3-alkyl-1,3-thiazolimines
TL;DR: In this paper, the reactions of ketones and N-substituted thioureas, in the presence of HCl (or HBr) and DMSO afford mixtures of the title compounds which are easily separated on a silica gel column.
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Assessing the nitrogen and carbon nucleophilicities of 2-aminothiazoles through coupling with superelectrophilic 4,6-dinitrobenzofuroxan.
Luciano Forlani,Aline Laure Tocke,Erminia Del Vecchio,Sami Lakhdar,Régis Goumont,François Terrier +5 more
TL;DR: Rate constants have been determined in the two solvents for the formation of the adducts, revealing a reactivity sequence which accounts well for the finding that 1a and 1b behave preferentially as carbon rather than nitrogen nucleophiles.
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Evidence for the Intermediacy of Wheland–Meisenheimer Complexes in SEAr Reactions of Aminothiazoles with 4,6-Dinitrobenzofuroxan
TL;DR: It is convincingly demonstrated that the structure of X combines the presence of a positively charged Wheland complex moiety (with regard to the thiazole ring) with that of a negatively charged Meisenheimer complex moieties (with regards to the benzofuroxan system).