M
Marcello Tiecco
Researcher at University of Perugia
Publications - 306
Citations - 5180
Marcello Tiecco is an academic researcher from University of Perugia. The author has contributed to research in topics: Nucleophile & Enantioselective synthesis. The author has an hindex of 38, co-authored 306 publications receiving 4944 citations. Previous affiliations of Marcello Tiecco include Autonomous University of Madrid & Sapienza University of Rome.
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Journal ArticleDOI
A convenient synthesis of aromatic thiols from unactivated aryl halides
TL;DR: Aromatic thiols are obtained in good yields from unactivated aryl halides and excess MeSNa in HMPA.
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Efficient asymmetric selenomethoxylation and selenohydroxylation of alkenes with a new sulfur containing chiral diselenide
Marcello Tiecco,Lorenzo Testaferri,Luana Bagnoli,Francesca Marini,Andrea Temperini,Cristina Tomassini,Claudio Santi +6 more
TL;DR: In this paper, the synthesis of a chiral non-racemic sulfur containing diselenide is described, and the electrophilic selenium reagent is used to effect selenomethoxylation and the selenohydroxylation of alkenes.
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Total synthesis of orellanine the lethal toxin of Cortinarius orellanus fries mushroom
TL;DR: Antkowiak and Gessner as mentioned in this paper reported the synthesis of the main toxin of Cortinarius Orellanus Fries, orellanine, and of its decomposition product, Orelline.
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Efficient asymmetric selenocyclizations of alkenyl oximes into cyclic nitrones and 1,2-oxazines promoted by sulfur containing diselenides
Marcello Tiecco,Lorenzo Testaferri,Luana Bagnoli,Valentina Purgatorio,Andrea Temperini,Francesca Marini,Claudio Santi +6 more
TL;DR: In this article, the ( E )- or ( Z )-geometry of the starting oximes was determined by the course of these reactions and hence the structures of the cyclization products were dictated by the (E)- or (Z)-geometry, and the two types of cyclization product were either the cyclic nitrones or the 1,2-oxazines.
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Synthesis of enantiomerically enriched β-hydroxy selenides by catalytic asymmetric ring opening of meso-epoxides with (phenylseleno)silanes
Marcello Tiecco,Lorenzo Testaferri,Francesca Marini,Silvia Sternativo,Francesca Del Verme,Claudio Santi,Luana Bagnoli,Andrea Temperini +7 more
TL;DR: In this paper, the first enantioselective ring opening of meso-epoxides by (phenylseleno)silanes using salen(Cr)complexes as catalyst is described.