M
Marie E. Krafft
Researcher at Florida State University
Publications - 140
Citations - 2440
Marie E. Krafft is an academic researcher from Florida State University. The author has contributed to research in topics: Pauson–Khand reaction & Catalysis. The author has an hindex of 29, co-authored 140 publications receiving 2375 citations. Previous affiliations of Marie E. Krafft include California State Polytechnic University, Pomona & University of California, Davis.
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When the Pauson-Khand and Pauson-Khand type reactions go awry: a plethora of unexpected results
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Effect of coordinating ligands on the Pauson-Khand cycloaddition: trapping of an intermediate
TL;DR: The Pauson-Khand cycloaddition has become a synthetically important reaction as discussed by the authors, and several modifications have increased the utility of the reaction, including reports that tertiary amine N-oxides greatly accelerate the rate of cycloadding in both intra- and some intermolecular reactions.
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A Convenient Protocol for the α-Iodination of α,β-Unsaturated Carbonyl Compounds with I2 in an Aqueous Medium
Marie E. Krafft,John W. Cran +1 more
TL;DR: A variety of cyclic and acyclic α,β-unsaturated carbonyl compounds undergo α-iodination exclusively, in high yields, with I 2 in aqueous THF catalyzed by DMAP and quinuclidine.
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The directed Pauson-Khand reaction
TL;DR: In this paper, it was shown that the regioselectivity of the cobalt-mediated cocyclization of an alkene, an alkyne, and carbon monoxide has been shown to be directed by the use of a soft atom, either sulfur or nitrogen, tethered to the alkene partner by a carbon chain.
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Organomediated Morita-Baylis-Hillman cyclization reactions.
TL;DR: The Morita-Baylis-Hillman reaction is developed to include, for the first time in a completely organomediated process, intramolecular examples bearing allylic leaving groups as the electrophilic partner providing a facile, high yielding, straightforward synthesis of densely functionalized cyclic molecules.