We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.

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Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene

The remarkable mechanical properties of carbon nanotubes arise from the exceptional strength and stiffness of the atomically thin carbon sheets (graphene) from which they are formed. In contrast, bulk graphite, a polycrystalline material, has low fracture strength and tends to suffer failure either by delamination of graphene sheets or at grain boundaries between the crystals. Now Stankovich et al. have produced an inexpensive polymer-matrix composite by separating graphene sheets from graphite and chemically tuning them. The material contains dispersed graphene sheets and offers access to a broad range of useful thermal, electrical and mechanical properties. Individual sheets of graphene can be readily incorporated into a polymer matrix, giving rise to composite materials having potentially useful electronic properties. Graphene sheets—one-atom-thick two-dimensional layers of sp2-bonded carbon—are predicted to have a range of unusual properties. Their thermal conductivity and mechanical stiffness may rival the remarkable in-plane values for graphite (∼3,000 W m-1 K-1 and 1,060 GPa, respectively); their fracture strength should be comparable to that of carbon nanotubes for similar types of defects1,2,3; and recent studies have shown that individual graphene sheets have extraordinary electronic transport properties4,5,6,7,8. One possible route to harnessing these properties for applications would be to incorporate graphene sheets in a composite material. The manufacturing of such composites requires not only that graphene sheets be produced on a sufficient scale but that they also be incorporated, and homogeneously distributed, into various matrices. Graphite, inexpensive and available in large quantity, unfortunately does not readily exfoliate to yield individual graphene sheets. Here we present a general approach for the preparation of graphene-polymer composites via complete exfoliation of graphite9 and molecular-level dispersion of individual, chemically modified graphene sheets within polymer hosts. A polystyrene–graphene composite formed by this route exhibits a percolation threshold10 of ∼0.1 volume per cent for room-temperature electrical conductivity, the lowest reported value for any carbon-based composite except for those involving carbon nanotubes11; at only 1 volume per cent, this composite has a conductivity of ∼0.1 S m-1, sufficient for many electrical applications12. Our bottom-up chemical approach of tuning the graphene sheet properties provides a path to a broad new class of graphene-based materials and their use in a variety of applications.

Graphene-based composite materials

http://nathan.instras.com/ResearchProposalDB/doc-109.pdf

A review on polymer nanofibers by electrospinning and their applications in nanocomposites

The tensile strengths of individual multiwalled carbon nanotubes (MWCNTs) were measured with a “nanostressing stage” located within a scanning electron microscope. The tensile-loading experiment was prepared and observed entirely within the microscope and was recorded on video. The MWCNTs broke in the outermost layer (“sword-in-sheath” failure), and the tensile strength of this layer ranged from 11 to 63 gigapascals for the set of 19 MWCNTs that were loaded. Analysis of the stress-strain curves for individual MWCNTs indicated that the Young's modulus E of the outermost layer varied from 270 to 950 gigapascals. Transmission electron microscopic examination of the broken nanotube fragments revealed a variety of structures, such as a nanotube ribbon, a wave pattern, and partial radial collapse.

https://science.sciencemag.org/content/sci/287/5453/637.full.pdf

Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load

This critical review provides a processing-structure-property perspective on recent advances in cellulose nanoparticles and composites produced from them. It summarizes cellulose nanoparticles in terms of particle morphology, crystal structure, and properties. Also described are the self-assembly and rheological properties of cellulose nanoparticle suspensions. The methodology of composite processing and resulting properties are fully covered, with an emphasis on neat and high fraction cellulose composites. Additionally, advances in predictive modeling from molecular dynamic simulations of crystalline cellulose to the continuum modeling of composites made with such particles are reviewed (392 references).

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Cellulose nanomaterials review: structure, properties and nanocomposites

The invention provides methods, compositions, and apparatus for performing sensitive detection of analytes, such as biological macromolecules and other analytes, by labeling a probe molecule with an up-converting label The up-converting label absorbs radiation from an illumination source and emits radiation at one or more higher frequencies, providing enhanced signal-to-noise ratio and the essential elimination of background sample autofluorescence The methods, compositions, and apparatus are suitable for the sensitive detection of multiple analytes and for various clinical and environmental sampling techniques

Up-converting reporters for biological and other assays using laser excitation techniques

A flat panel display (1001) is based on a new switching technology for routing laser light from a laser light source (1000) through an array of optical energy routers (1008) among a set of optical waveguides (1014) and coupling light toward the viewer. The switching technology is based on poled electro-optic structures. The display technology is versatile enough to cover application areas spanning the range from miniature high resolution computer display to large screen displays for high definition television (HDTV) formats. The invention combines the high brightness and power efficiency inherent in visible semiconductor diode laser sources with a new waveguide electro-optical switching technology to form a dense two-dimensional addressable array of high brightness light emissive pixels.

Display panel with electrically-controlled waveguide-routing

Carbon nanotubes are manipulated in three dimensions inside a scanning electron microscope (SEM). A custom piezoelectric vacuum manipulator achieves positional resolutions comparable to scanning probe microscopes, with the ability to manipulate objects along one rotational and three linear degrees of freedom. This prototypical device can probe, select and handle nanometre-scale objects such as carbon nanotubes in order to explore and correlate their mechanical and electrical properties. Under real-time SEM inspection, carbon nanotubes are stressed while monitoring their conductivity, and nanotubes are attached to commercial atomic force microscope (AFM) tips such that the forces applied to the tubes can be measured from the cantilevers' deflections. The manipulator functions both as a research tool for investigating properties of carbon nanotubes and other nanoscale objects without surface restrictions, and as a rudimentary building device for larger nanotube assemblies. This capability to select and manipulate nanoscale components and to examine directly their suitability as construction materials during various phases of the construction process will play an important role in enabling the technology of assembling mechanical and electronic devices from prefabricated components.

/pdf/three-dimensional-manipulation-of-carbon-nanotubes-under-a-4pahgjc7vc.pdf

Three-dimensional manipulation of carbon nanotubes under a scanning electron microscope

A method for obtaining a two-dimensional image of laser-induced fluorescence of a naturally occurring flame radical is described. A tunable laser beam is focused by a cylindrical lens into a sheet that passes through the flame, exciting OH lying within the plane defined by the laser. The fluorescence at right angles is imaged onto an intensified vidicon tube, forming a map of the ground-state OH concentration within the flame. For a sheet 0.5 mm thick, up to 2800 counts/mm2 of flame area are obtained on a single laser pulse for an OH concentration of 700 parts in 106. The method holds considerable promise for imaging in time-varying systems, such as reactive turbulent combustion.

Mark J. Dyer

Papers

Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load

Up-converting reporters for biological and other assays using laser excitation techniques

Display panel with electrically-controlled waveguide-routing

Three-dimensional manipulation of carbon nanotubes under a scanning electron microscope

Two-dimensional imaging of OH laser-induced fluorescence in a flame.