The applications of copper (Cu) and Cu-based nanoparticles, which are based on the earth-abundant and inexpensive copper metal, have generated a great deal of interest in recent years, especially in the field of catalysis. The possible modification of the chemical and physical properties of these nanoparticles using different synthetic strategies and conditions and/or via postsynthetic chemical treatments has been largely responsible for the rapid growth of interest in these nanomaterials and their applications in catalysis. In addition, the design and development of novel support and/or multimetallic systems (e.g., alloys, etc.) has also made significant contributions to the field. In this comprehensive review, we report different synthetic approaches to Cu and Cu-based nanoparticles (metallic copper, copper oxides, and hybrid copper nanostructures) and copper nanoparticles immobilized into or supported on various support materials (SiO2, magnetic support materials, etc.), along with their applications i...

http://pubs.acs.org/doi/pdfplus/10.1021/acs.chemrev.5b00482

Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis.

Heavy metal removal from aqueous solution by advanced carbon nanotubes: Critical review of adsorption applications

Graphene is a well-known two-dimensional material that exhibits preeminent electrical, mechanical and thermal properties owing to its unique one-atom-thick structure. Graphene and its derivatives (e.g., graphene oxide) have become emerging nano-building blocks for separation membranes featuring distinct laminar structures and tunable physicochemical properties. Extraordinary molecular separation properties for purifying water and gases have been demonstrated by graphene-based membranes, which have attracted a huge surge of interest during the past few years. This tutorial review aims to present the latest groundbreaking advances in both the theoretical and experimental chemical science and engineering of graphene-based membranes, including their design, fabrication and application. Special attention will be given to the progresses in processing graphene and its derivatives into separation membranes with three distinct forms: a porous graphene layer, assembled graphene laminates and graphene-based composites. Moreover, critical views on separation mechanisms within graphene-based membranes will be provided based on discussing the effect of inter-layer nanochannels, defects/pores and functional groups on molecular transport. Furthermore, the separation performance of graphene-based membranes applied in pressure filtration, pervaporation and gas separation will be summarized. This article is expected to provide a compact source of relevant and timely information and will be of great interest to all chemists, physicists, materials scientists, engineers and students entering or already working in the field of graphene-based membranes and functional films.

Graphene-based membranes

https://cronfa.swan.ac.uk/Record/cronfa48864/Download/0048864-07032019141310.pdf

Reverse osmosis desalination: A state-of-the-art review

The fabrication of photoluminescent Ti3 C2 MXene quantum dots (MQDs) by a facile hydrothermal method is reported, which may greatly extend the applications of MXene-based materials. Interestingly, the as-prepared MQDs show excitation-dependent photoluminescence spectra with quantum yields of up to ≈10% due to strong quantum confinement. The applications of MQDs as biocompatible multicolor cellular imaging probes and zinc ion sensors are demonstrated.

Photoluminescent Ti3C2 MXene Quantum Dots for Multicolor Cellular Imaging

Functional graphene nanosheets: The next generation membranes for water desalination

Friction stir processing of commercial AZ31 magnesium alloy

Inorganic membrane science and technology is an attractive field of membrane separation technology, which has been dominated by polymer membranes. Recently, the inorganic membrane has been undergoing rapid development and innovation. Inorganic membranes have the advantage of resisting harsh chemical cleaning, high temperature and wear resistance, high chemical stability, long lifetime, and autoclavable. All of these outstanding properties made inorganic membranes good candidates to be used for water treatment and desalination applications. This paper is a state of the art review on the synthesis, development, and application of different inorganic membranes for water and wastewater treatment. The inorganic membranes reviewed in this paper include liquid membranes, dynamic membranes, various ceramic membranes, carbon based membranes, silica membranes, and zeolite membranes. A brief description of the different synthesis routes for the development of inorganic membranes for application in water industry is given and each synthesis rout is critically reviewed and compared. Thereafter, the recent studies on different application of inorganic membrane and their properties for water treatment and desalination in literature are critically summarized. It was reported that inorganic membranes despite their high synthesis cost, showed very promising results with high flux, full salt rejection, and very low or no fouling.

https://www.mdpi.com/1996-1944/11/1/74/pdf

Inorganic Membranes: Preparation and Application for Water Treatment and Desalination.

https://cronfa.swan.ac.uk/Record/cronfa29220/Download/0029220-01082016091848.pdf

Mechanical properties of water desalination and wastewater treatment membranes

It is well documented that applying mechanical vibration to the mold during solidification has a profound effect on the microstructure and mechanical properties of castings. However, it is still not well understood how mechanical vibration change the resulting microstructure. Most of the available studies are qualitative and provide little quantitative information that can be used by the casting industry. In this work, mechanical mold vibration is applied to an Al–Si eutectic (Al–12.5% Si) alloy at a frequency of 100 Hz and variable amplitudes in the range of 18–199 μm. It is shown that the silicon morphology was strongly influenced by the level of vibration amplitude. Generally, increasing the vibration amplitude tends to reduce the lamellar spacing and change the silicon morphology to become more fibrous. However, exceeding a critical value of vibration amplitude tends to coarsen the silicon. The corresponding changes in mechanical properties are also investigated. It is shown that the maximum elongation is more influenced by vibration than the tensile strength for the range of conditions tested here.

Marwan K. Khraisheh

Papers

Functional graphene nanosheets: The next generation membranes for water desalination

Friction stir processing of commercial AZ31 magnesium alloy

Inorganic Membranes: Preparation and Application for Water Treatment and Desalination.

Mechanical properties of water desalination and wastewater treatment membranes

Silicon morphology modification in the eutectic Al-Si alloy using mechanical mold vibration