This paper reviews the development of latent heat thermal energy storage systems studied detailing various phase change materials (PCMs) investigated over the last three decades, the heat transfer and enhancement techniques employed in PCMs to effectively charge and discharge latent heat energy and the formulation of the phase change problem. It also examines the geometry and configurations of PCM containers and a series of numerical and experimental tests undertaken to assess the effects of parameters such as the inlet temperature and the mass flow rate of the heat transfer fluid (HTF). It is concluded that most of the phase change problems have been carried out at temperature ranges between 0 °C and 60 °C suitable for domestic heating applications. In terms of problem formulation, the common approach has been the use of enthalpy formulation. Heat transfer in the phase change problem was previously formulated using pure conduction approach but the problem has moved to a different level of complexity with added convection in the melt being accounted for. There is no standard method (such as British Standards or EU standards) developed to test for PCMs, making it difficult for comparison to be made to assess the suitability of PCMs to particular applications. A unified platform such as British Standards, EU standards needs to be developed to ensure same or similar procedure and analysis (performance curves) to allow comparison and knowledge gained from one test to be applied to another.

A review of materials, heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS)

Phase change materials for thermal energy storage

Thermal energy storage technologies and systems for concentrating solar power plants

A review of experimental/computational studies to enhance the thermal conductivity of phase change materials (PCM) that were conducted over many decades is presented. Thermal management of electronics for aeronautics and space exploration appears to be the original intended application, with later extension to storage of thermal energy for solar thermal applications. The present review will focus on studies that concern with positioning of fixed, stationary high conductivity inserts/structures. Copper, aluminum, nickel, stainless steel and carbon fiber in various forms (fins, honeycomb, wool, brush, etc.) were generally utilized as the materials of the thermal conductivity promoters. The reviewed research studies covered a variety of PCM, operating conditions, heat exchange and thermal energy storage arrangements. The energy storage vessels included isolated thermal storage units (rectangular boxes, cylindrical and annular tubes and spheres) and containers that transferred heat to a moving fluid medium passing through it. A few studies have focused on the marked role of flow regimes that are formed due to the presence of thermally unstable fluid layers that in turn give rise to greater convective mixing and thus expedited melting of PCM. In general, it can be stated that due to utilization of fixed high conductivity inserts/structures, the conducting pathways linking the hot and cold ends must be minimized.

Thermal conductivity enhancement of phase change materials for thermal energy storage: A review ☆

Thermal comfort and building energy consumption implications - A review

A comparison of heat transfer enhancement in a medium temperature thermal energy storage heat exchanger using fins

Heat transfer enhancement in medium temperature thermal energy storage system using a multitube heat transfer array

Long term performance analysis of a grid connected photovoltaic system in Northern Ireland

Experimental study on the melting and solidification behaviour of a medium temperature phase change storage material (Erythritol) system augmented with fins to power a LiBr/H2O absorption cooling system

Mervyn Smyth

Papers

A review of materials, heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS)

A comparison of heat transfer enhancement in a medium temperature thermal energy storage heat exchanger using fins

Heat transfer enhancement in medium temperature thermal energy storage system using a multitube heat transfer array

Long term performance analysis of a grid connected photovoltaic system in Northern Ireland

Experimental study on the melting and solidification behaviour of a medium temperature phase change storage material (Erythritol) system augmented with fins to power a LiBr/H2O absorption cooling system