Biocomposites reinforced with natural fibers: 2000–2010

There have been a number of review papers on layered silicate and carbon nanotube reinforced polymer nanocomposites, in which the fillers have high aspect ratios. Particulate–polymer nanocomposites containing fillers with small aspect ratios are also an important class of polymer composites. However, they have been apparently overlooked. Thus, in this paper, detailed discussions on the effects of particle size, particle/matrix interface adhesion and particle loading on the stiffness, strength and toughness of such particulate–polymer composites are reviewed. To develop high performance particulate composites, it is necessary to have some basic understanding of the stiffening, strengthening and toughening mechanisms of these composites. A critical evaluation of published experimental results in comparison with theoretical models is given.

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Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites

Electrolytes have been identified as some of the most influential components in the performance of electrochemical supercapacitors (ESs), which include: electrical double-layer capacitors, pseudocapacitors and hybrid supercapacitors. This paper reviews recent progress in the research and development of ES electrolytes. The electrolytes are classified into several categories, including: aqueous, organic, ionic liquids, solid-state or quasi-solid-state, as well as redox-active electrolytes. Effects of electrolyte properties on ES performance are discussed in detail. The principles and methods of designing and optimizing electrolytes for ES performance and application are highlighted through a comprehensive analysis of the literature. Interaction among the electrolytes, electro-active materials and inactive components (current collectors, binders, and separators) is discussed. The challenges in producing high-performing electrolytes are analyzed. Several possible research directions to overcome these challenges are proposed for future efforts, with the main aim of improving ESs' energy density without sacrificing existing advantages (e.g., a high power density and a long cycle-life) (507 references).

A review of electrolyte materials and compositions for electrochemical supercapacitors

Studies on the use of natural fibers as replacement to man-made fiber in fiber-reinforced composites have increased and opened up further industrial possibilities. Natural fibers have the advantages of low density, low cost, and biodegradability. However, the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative high moisture sorption. Therefore, chemical treatments are considered in modifying the fiber surface properties. In this paper, the different chemical modifications on natural fibers for use in natural fiber-reinforced composites are reviewed. Chemical treatments including alkali, silane, acetylation, benzoylation, acrylation, maleated coupling agents, isocyanates, permanganate and others are discussed. The chemical treatment of fiber aimed at improving the adhesion between the fiber surface and the polymer matrix may not only modify the fiber surface but also increase fiber strength. Water absorption of composites is reduced and their mechanical properties are improved.

Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review

This paper provides an overview of recent progress made in the area of cellulose nanofibre-based nanocomposites. An introduction into the methods used to isolate cellulose nanofibres (nanowhiskers, nanofibrils) is given, with details of their structure. Following this, the article is split into sections dealing with processing and characterisation of cellulose nanocomposites and new developments in the area, with particular emphasis on applications. The types of cellulose nanofibres covered are those extracted from plants by acid hydrolysis (nanowhiskers), mechanical treatment and those that occur naturally (tunicate nanowhiskers) or under culturing conditions (bacterial cellulose nanofibrils). Research highlighted in the article are the use of cellulose nanowhiskers for shape memory nanocomposites, analysis of the interfacial properties of cellulose nanowhisker and nanofibril-based composites using Raman spectroscopy, switchable interfaces that mimic sea cucumbers, polymerisation from the surface of cellulose nanowhiskers by atom transfer radical polymerisation and ring opening polymerisation, and methods to analyse the dispersion of nanowhiskers. The applications and new advances covered in this review are the use of cellulose nanofibres to reinforce adhesives, to make optically transparent paper for electronic displays, to create DNA-hybrid materials, to generate hierarchical composites and for use in foams, aerogels and starch nanocomposites and the use of all-cellulose nanocomposites for enhanced coupling between matrix and fibre. A comprehensive coverage of the literature is given and some suggestions on where the field is likely to advance in the future are discussed.

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Review: current international research into cellulose nanofibres and nanocomposites

Surfaces of nano-silica particles can be effectively modified by means of irradiation graft polymerization. When polypropylene (PP) was compounded with these treated nanoparticles, an overall improvement in the mechanical properties of the composites at rather low filler content was acquired. The present work observed the deformation characteristics of the PP nanocomposites using transmission electron microscope. Due to the interfacial entanglement between the grafting polymers attached to the nanoparticles and the matrix polymer, the grafted nano-SiO 2 exhibits much greater extensibility in the composites than the nanoparticles as-received. It is believed to be the main cause of extensive plastic drawing of the matrix polymer surrounding the treated nanoparticles, and it provides the composites with higher static ductility.

Deformation characteristics of nano-SiO2 filled polypropylene composites

Basics of Self‐Healing: State of the Art

The dynamic process of cold crystallization of amorphous poly(trimethylene terephthalate) (PTT) was investigated with resonance light scattering (RLS). By using an enhanced scattering peak at 329 nm, which was in close proximity to the absorption band of PTT film, density fluctuation due to gradual transition from amorphous to crystalline with increasing temperature was monitored. Accordingly, molecular chains movement and structure evolution in PTT during cold crystallization, in particular, the information about each phase of crystallization, including induction, nucleation, nucleus growth and secondary crystallization, were thoroughly revealed. The experimental results indicated that the kinetics parameters measured by the RLS method were in good agreement with those obtained by differential scanning calorimetry (DSC) and fluorescence spectroscopy. In addition, the RLS method can tell more details of the movement and variation in fine structures than DSC and fluorescence techniques as a result of its significantly enhanced scattering signals, like the orientation fluctuations of rigid segments in the course of glass transition and crystallization induction.

Evolution of density fluctuation to a lamellar crystal in a poly(trimethylene terephthalate) film revealed by the resonance light scattering technique

Nanopore separator of cross-linked poly(propylene glycol)-co-pentaerythritol triacrylate for effectively suppressing polysulfide shuttling in Li–S batteries

Ming Qiu Zhang

Papers

Deformation characteristics of nano-SiO2 filled polypropylene composites

Basics of Self‐Healing: State of the Art

Evolution of density fluctuation to a lamellar crystal in a poly(trimethylene terephthalate) film revealed by the resonance light scattering technique

Nanopore separator of cross-linked poly(propylene glycol)-co-pentaerythritol triacrylate for effectively suppressing polysulfide shuttling in Li–S batteries

Acoustic emission study of the TDCB test of microcapsules filled self-healing polymer