M
Minxue Huang
Researcher at University of Wisconsin-Madison
Publications - 6
Citations - 204
Minxue Huang is an academic researcher from University of Wisconsin-Madison. The author has contributed to research in topics: Nitrene & Amination. The author has an hindex of 6, co-authored 6 publications receiving 142 citations. Previous affiliations of Minxue Huang include Nanjing Tech University.
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Journal ArticleDOI
Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.
TL;DR: The underlying reasons why Ag(tpa)OTf (tpa = tris(pyridylmethyl)amine) prefers to activate α-conjugated C-H bonds over 3° alkyl C(sp3)-H bonds are explored and the possible roles of noncovalent interactions (NCIs) in directing the NT are suggested.
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Silver-Catalyzed Enantioselective Propargylic C-H Bond Amination through Rational Ligand Design.
Minsoo Ju,Emily E. Zerull,Jessica M. Roberts,Minxue Huang,Ilia A. Guzei,Jennifer M. Schomaker +5 more
TL;DR: A regio- and enantioselective synthesis of -alkynyl -aminoalcohols via a silver-catalyzed propargylic C-H amination, which furnishes versatile products in good yields and excellent enantiOSElectivity (90-99% ee).
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Novel 3D lanthanide-organic frameworks with an unusual infinite nanosized ribbon [Ln3(μ3–OH)2(–CO2)6]+n (Ln = Eu, Gd, Dy): syntheses, structures, luminescence, and magnetic properties
Hai-Juan Zhang,Xiao-Zhu Wang,Dun-Ru Zhu,Dun-Ru Zhu,You Song,Yan Xu,Heng Xu,Xuan Shen,Ting Gao,Minxue Huang +9 more
TL;DR: In this article, three novel lanthanide-organic frameworks, [Ln3(μ3-OH)2L2(HCO2)3(H2O)2]·H2•O (Ln = Eu (1), Gd (2), Dy (3); H2L = 3,3′-dimethoxy-4,4′-biphenyldicarboxylic acid), have been prepared by the solvothermal reaction of Ln(NO3)3·6H 2O and H
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Synthesis, Characterization, and Variable-Temperature NMR Studies of Silver(I) Complexes for Selective Nitrene Transfer
Minxue Huang,Joshua R. Corbin,Nicholas S. Dolan,Charles G. Fry,Anastasiya I. Vinokur,Ilia A. Guzei,Jennifer M. Schomaker +6 more
TL;DR: X-ray structural characterizations were helpful in determining ligand features that promote the formation of monomeric versus dimeric complexes, and Variable-temperature 1H and DOSY NMR experiments were especially useful for understanding how the ligand identity influences the nuclearity, coordination number, and fluxional behavior of silver(I) complexes in solution.
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Tunable catalyst-controlled syntheses of β- and γ-amino alcohols enabled by silver-catalysed nitrene transfer
Minsoo Ju,Minxue Huang,Logan E. Vine,Mahzad Dehghany,Jessica M. Roberts,Jennifer M. Schomaker +5 more
TL;DR: Two complementary silver catalysts are reported that are capable of selecting between β- or γ-C–H bonds that reside in similar steric/electronic environments, overriding a reaction at a weaker C–H bond in favour of a stronger one and activating primary C-H bonds.