Monami Maiti

TL;DR: The hydrazone Schiff base ligands have been used to synthesize the following MnII complexes: the mononuclear complex [Mn(HL1 )2][ClO4]2· 2H2O (1), the cocrystallized discrete dinuclear complex {[Mn[HL1 ]2]· [mn(L 1 ]2]}[ClO 4]2]2 (2), and the phenoxido-bridged dinuclear Complex [Mm(μ•HL2 )(H 2O)]2[Cl

TL;DR: Four new dicyanamide (dca) bridged multinuclear Zn(II)-Schiff-base complexes, synthesized using four different Schiff bases, have been characterized by microanalytical and spectroscopic techniques and conclusively determined by single crystal X-ray diffraction studies.

TL;DR: In this paper, a single thiocyanato bridged 1D polymeric zinc complex with dinuclear asymmetric unit was synthesized using two different Schiff bases N,N/-bis(3-methoxysalicylidenimino)-1,3-diaminopropane (L1H2) and N, N/-bis (3-ethoxyaliclyideniminos)-1.3-diagrams (L2H2), respectively.

TL;DR: In this article, a tetragonally elongated octahedral geometry for the manganese coordination sphere was characterized and the octahedron entities were further connected in pairs through intermolecular hydrogen bonding to form μ-aquo dimers.

TL;DR: In this paper, three new hetero-bimetallic coordination complexes have been characterized by microanalytical and spectroscopic techniques, and the optimized geometries of the complexes were carried out at the BLYP/DNP level to determine their relative stabilities from the HOMO LUMO gap and chemical softness values.