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Nathalie Audebrand

Researcher at University of Rennes

Publications -  100
Citations -  4180

Nathalie Audebrand is an academic researcher from University of Rennes. The author has contributed to research in topics: Crystal structure & Powder diffraction. The author has an hindex of 25, co-authored 94 publications receiving 3712 citations. Previous affiliations of Nathalie Audebrand include Centre national de la recherche scientifique & École Polytechnique Fédérale de Lausanne.

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Role of solvent-host interactions that lead to very large swelling of hybrid frameworks

TL;DR: In situ techniques show that these flexible solids are highly selective absorbents and that this selectivity is strongly dependent on the nature of the organic linker.
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MIL-103, a 3-D lanthanide-based metal organic framework with large one-dimensional tunnels and a high surface area.

TL;DR: A lanthanide-based metal organic framework, formulated Tb(C27H15O6)(H2O).2C6H11OH, has been solvothermally synthesized using the extended rigid tritopic ligand 1,3,5-tribenzoate to present large 1-D micropores and a high surface area.
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Investigation of acid sites in a zeotypic giant pores chromium(III) carboxylate.

TL;DR: The thermal behavior of the zeotypic giant pores chromium(III) tricarboxylate (MIL-100) indicates that the departure of water occurs without any pore contraction and no loss in crystallinity, which confirms the robustness of the framework.
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Very Large Swelling in Hybrid Frameworks: A Combined Computational and Powder Diffraction Study

TL;DR: The crystal structure of the open form of MIL-88 has been successfully refined and indicates that atomic displacements larger than 4 angstroms are observed when water or various alcohols are adsorbed in the porous structure, revealing an unusually flexible crystallized framework.
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The Kagomé topology of the gallium and indium metal-organic framework types with a MIL-68 structure: synthesis, XRD, solid-state NMR characterizations, and hydrogen adsorption.

TL;DR: The vanadium-based terephthalate analogs of MIL-68 have been obtained with gallium and indium by using a solvothermal synthesis technique using N,N-dimethylformamide as a solvent to characterize the materials and reveal important information on the spatial arrangement of the guest species with respect to the hybrid organic-inorganic network.