Nevin Gürbüz

TL;DR: In this article, the reaction of [Rh( μ -Cl)(cod)] 2 and Ir( η 5 -C 5 Me 5 )( μ-Cl)Cl] 2 with aminophosphine ligands Cy 2 PNHCH 2 -C 4 H 3 X (X: O; S) gave a range of new monodendate complexes, which were characterized by analytical and spectroscopic methods.

TL;DR: In this article, a series of palladium N-heterocyclic carbene complexes with methoxyethyl on the side chain (3a-d, 4a-e, 4b) have been synthesized and fully characterized by NMR, HRMS and IR.

TL;DR: In this article, new benzimidazolium sulfonate salts have been prepared and fully characterized and they have been associated in situ with [RuCl2(p-cymene)]2 to generate efficient catalytic systems operating at 120 °C under neat conditions in the presence of potassium tert-butylate for selective N-alkylation of primary aromatic amines into secondary amines.

TL;DR: In this article, the bis(phosphino)amine ligands (Ph2P)2N-C6H3-R, where R = 3,5-OMe (1), 2,5-, 2,4-OME (2), 3,4-, or 3, 4-, were prepd. via aminolysis of the corresponding dimethoxyanilines with 2 equiv.

TL;DR: In this paper, a review of new developments reported during the last three years concerning the catalytic performances of in situ formed or preformed NHC-Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shorten to the Suzuki reaction), Sonogashira and Hiyama couplings, and Buchwald--Hartwig aminations, which are