Nicola Magnani

TL;DR: The first observation of such low-temperature magnetic memory effects in another transuranic molecular complex is reported, namely, bis(cyclooctatetraenyl)neptunium(IV), commonly known as neptunocene, which was first described in 1970 and belongs to the whole actinocene row.

TL;DR: The synthesis, structure, reactivity and magnetic properties of a binuclear uranium-oxo complex are described and the new butterfly-shaped Si-OUO(2)UO-Si molecule shows remarkably strong U(V)-U(V) coupling and chemical inertness, suggesting that this rearranged uranium oxo motif might exist for other actinides species in the environment, and have relevance to the aggregation of actinide oxide clusters.

TL;DR: In this article, a single-electron reduction of the Pacman uranyl complex [UO2(py)(H2L)] by the rare-earth complexes Ln(III)(A)3 (A = N(SiMe3)2, OC6H3Bu(t)2-2,6) via homolysis of a Ln-A bond was proposed.