This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

This review describes a new paradigm of electronics based on the spin degree of freedom of the electron. Either adding the spin degree of freedom to conventional charge-based electronic devices or using the spin alone has the potential advantages of nonvolatility, increased data processing speed, decreased electric power consumption, and increased integration densities compared with conventional semiconductor devices. To successfully incorporate spins into existing semiconductor technology, one has to resolve technical issues such as efficient injection, transport, control and manipulation, and detection of spin polarization as well as spin-polarized currents. Recent advances in new materials engineering hold the promise of realizing spintronic devices in the near future. We review the current state of the spin-based devices, efforts in new materials fabrication, issues in spin transport, and optical spin manipulation.

http://science.sciencemag.org/content/sci/294/5546/1488.full.pdf

Spintronics: a spin-based electronics vision for the future.

Spintronics, or spin electronics, involves the study of active control and manipulation of spin degrees of freedom in solid-state systems. This article reviews the current status of this subject, including both recent advances and well-established results. The primary focus is on the basic physical principles underlying the generation of carrier spin polarization, spin dynamics, and spin-polarized transport in semiconductors and metals. Spin transport differs from charge transport in that spin is a nonconserved quantity in solids due to spin-orbit and hyperfine coupling. The authors discuss in detail spin decoherence mechanisms in metals and semiconductors. Various theories of spin injection and spin-polarized transport are applied to hybrid structures relevant to spin-based devices and fundamental studies of materials properties. Experimental work is reviewed with the emphasis on projected applications, in which external electric and magnetic fields and illumination by light will be used to control spin and charge dynamics to create new functionalities not feasible or ineffective with conventional electronics.

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Spintronics: Fundamentals and applications

Graphene devices on standard SiO(2) substrates are highly disordered, exhibiting characteristics that are far inferior to the expected intrinsic properties of graphene. Although suspending the graphene above the substrate leads to a substantial improvement in device quality, this geometry imposes severe limitations on device architecture and functionality. There is a growing need, therefore, to identify dielectrics that allow a substrate-supported geometry while retaining the quality achieved with a suspended sample. Hexagonal boron nitride (h-BN) is an appealing substrate, because it has an atomically smooth surface that is relatively free of dangling bonds and charge traps. It also has a lattice constant similar to that of graphite, and has large optical phonon modes and a large electrical bandgap. Here we report the fabrication and characterization of high-quality exfoliated mono- and bilayer graphene devices on single-crystal h-BN substrates, by using a mechanical transfer process. Graphene devices on h-BN substrates have mobilities and carrier inhomogeneities that are almost an order of magnitude better than devices on SiO(2). These devices also show reduced roughness, intrinsic doping and chemical reactivity. The ability to assemble crystalline layered materials in a controlled way permits the fabrication of graphene devices on other promising dielectrics and allows for the realization of more complex graphene heterostructures.

Boron nitride substrates for high-quality graphene electronics

BACKGROUND Materials by design is an appealing idea that is very hard to realize in practice. Combining the best of different ingredients in one ultimate material is a task for which we currently have no general solution. However, we do have some successful examples to draw upon: Composite materials and III-V heterostructures have revolutionized many aspects of our lives. Still, we need a general strategy to solve the problem of mixing and matching crystals with different properties, creating combinations with predetermined attributes and functionalities. ADVANCES Two-dimensional (2D) materials offer a platform that allows creation of heterostructures with a variety of properties. One-atom-thick crystals now comprise a large family of these materials, collectively covering a very broad range of properties. The first material to be included was graphene, a zero-overlap semimetal. The family of 2D crystals has grown to includes metals (e.g., NbSe 2 ), semiconductors (e.g., MoS 2 ), and insulators [e.g., hexagonal boron nitride (hBN)]. Many of these materials are stable at ambient conditions, and we have come up with strategies for handling those that are not. Surprisingly, the properties of such 2D materials are often very different from those of their 3D counterparts. Furthermore, even the study of familiar phenomena (like superconductivity or ferromagnetism) in the 2D case, where there is no long-range order, raises many thought-provoking questions. A plethora of opportunities appear when we start to combine several 2D crystals in one vertical stack. Held together by van der Waals forces (the same forces that hold layered materials together), such heterostructures allow a far greater number of combinations than any traditional growth method. As the family of 2D crystals is expanding day by day, so too is the complexity of the heterostructures that could be created with atomic precision. When stacking different crystals together, the synergetic effects become very important. In the first-order approximation, charge redistribution might occur between the neighboring (and even more distant) crystals in the stack. Neighboring crystals can also induce structural changes in each other. Furthermore, such changes can be controlled by adjusting the relative orientation between the individual elements. Such heterostructures have already led to the observation of numerous exciting physical phenomena. Thus, spectrum reconstruction in graphene interacting with hBN allowed several groups to study the Hofstadter butterfly effect and topological currents in such a system. The possibility of positioning crystals in very close (but controlled) proximity to one another allows for the study of tunneling and drag effects. The use of semiconducting monolayers leads to the creation of optically active heterostructures. The extended range of functionalities of such heterostructures yields a range of possible applications. Now the highest-mobility graphene transistors are achieved by encapsulating graphene with hBN. Photovoltaic and light-emitting devices have been demonstrated by combining optically active semiconducting layers and graphene as transparent electrodes. OUTLOOK Currently, most 2D heterostructures are composed by direct stacking of individual monolayer flakes of different materials. Although this method allows ultimate flexibility, it is slow and cumbersome. Thus, techniques involving transfer of large-area crystals grown by chemical vapor deposition (CVD), direct growth of heterostructures by CVD or physical epitaxy, or one-step growth in solution are being developed. Currently, we are at the same level as we were with graphene 10 years ago: plenty of interesting science and unclear prospects for mass production. Given the fast progress of graphene technology over the past few years, we can expect similar advances in the production of the heterostructures, making the science and applications more achievable.

2D materials and van der Waals heterostructures

Femtosecond bleaching measurements are performed in n-doped GaAs at both 300 K and 14 K using low densities of carriers injected at 2 eV. The dwell time of electrons excited far above the Fermi sea is reduced because of hot-electron/cold-electron interactions. The response at 14 K is much stronger and slower than that at 300 K. This is attributed to: (i) the proximity to the Fermi level of the conduction band states probed via split-off valence band coupling; (ii) slow Landau damping of non-equilibrium plasmons, primarily by the minority holes which then heat the majority electrons.

https://iopscience.iop.org/article/10.1088/0268-1242/9/5S/015/pdf

Hot carrier dynamics near the Fermi edge of n-doped GaAs

We extract local current distributions from interatomic currents calculated using a fully relativistic quantum mechanical scattering formalism by interpolation onto a three-dimensional grid. The method is illustrated with calculations for Pt|Ir and Pt|Au multilayers as well as for thin films of Pt and Au that include temperature-dependent lattice disorder. The current flow is studied in the "classical"and "Knudsen"limits determined by the sample thickness relative to the mean free path λ, introducing current streamlines to visualize the results. For periodic multilayers, our results in the classical limit reveal that transport inside a metal can be described using a single value of resistivity ρ combined with a linear variation of ρ at the interface while the Knudsen limit indicates a strong spatial dependence of ρ inside a metal and an anomalous dip of the current density at the interface which is accentuated in a region where shunting is incomplete.

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Fully resolved currents from quantum transport calculations

The magnetocrystalline anisotropy energies of [001] and [111] oriented ConPdm multilayers (with n+m≤6) have been calculated from first principles using the linear muffin-tin orbital method in the atomic-spheres approximation together with the local-spin-density approximation. While the easy axes of all [111] ConPdm multilayers considered are found to be perpendicular to the film plane, [001] ConPdm multilayers are only found to be perpendicularly magnetized if they contain cobalt as monolayers. The magnetocrystalline anisotropy energy is calculated to be largest for [111] Co1Pd2 and decreases with increasing Co thickness. These predictions are in agreement with experiment.

First-Principles Calculation of the Magnetocrystalline Anisotropy Energy of ConPdm Multilayers

The density dependence of the initial scattering rate of free carriers within nearly monoenergetic distributions is studied both experimentally and theoretically in bulk GaAs. The net decay rate of the population at the centre of such athermal distributions due to carrier-carrier scattering within the distribution is found to increase slowly, as the density of carriers to the power 0.3+or-0.1. The calculated result, which is quite insensitive to the approximation used to treat the screening of the Coulomb interaction, indicates that this carrier-carrier scattering rate increases significantly with the mean energy of the athermal distribution.

Paul J. Kelly

Papers

Hot carrier dynamics near the Fermi edge of n-doped GaAs

Fully resolved currents from quantum transport calculations

First-Principles Calculation of the Magnetocrystalline Anisotropy Energy of ConPdm Multilayers

Carrier-carrier scattering within athermal distributions

Efficient spin injection from Fe into InAs