P
Peter Fristrup
Researcher at Technical University of Denmark
Publications - 96
Citations - 3594
Peter Fristrup is an academic researcher from Technical University of Denmark. The author has contributed to research in topics: Catalysis & Allylic rearrangement. The author has an hindex of 36, co-authored 96 publications receiving 3178 citations. Previous affiliations of Peter Fristrup include Copenhagen Business School & California Institute of Technology.
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Metal‐Free Dehydration of Glucose to 5‐(Hydroxymethyl)furfural in Ionic Liquids with Boric Acid as a Promoter
TL;DR: The introduced non-metal system containing boric acid provides a new direction in the search for catalyst systems allowing efficient HMF formation from biorenewable sources.
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The mechanism for the rhodium-catalyzed decarbonylation of aldehydes: a combined experimental and theoretical study.
TL;DR: The theoretical kinetic isotope effects based on this mechanism were in excellent agreement with the experimental values for both substrates, but only when migratory extrusion of CO was selected as the rate-determining step.
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Theoretical Evidence for Low-Ligated Palladium(0): [Pd−L] as the Active Species in Oxidative Addition Reactions
TL;DR: In this paper, Weinhold and Landis showed that p-orbitals on the central metal are not involved in bonding in any of the complexes described herein, in good agreement with classic ligand field theory and also with a recent bonding analysis.
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Tin-containing Silicates: Alkali Salts Improve Methyl Lactate Yield from Sugars
Søren Tolborg,Irantzu Sádaba,Christian Mårup Osmundsen,Peter Fristrup,Martin Spangsberg Holm,Esben Taarning +5 more
TL;DR: The beneficial effect of adding alkali to the reaction media applies not only to highly defect-free Sn-Beta prepared through the fluoride route, but also to materials prepared by post-treatment of dealuminated commercial Beta zeolites, as well as ordered mesoporous stannosilicates, in this case Sn-MCM-41 and Sn-SBA-15.
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Cis–Trans Amide Bond Rotamers in β-Peptoids and Peptoids: Evaluation of Stereoelectronic Effects in Backbone and Side Chains
TL;DR: An investigation of the effect of structural variations on the cis-trans amide bond rotamer equilibria in a selection of monomer model systems revealed an increase in the preference for cis-amides as compared to their parent compounds and thus provide novel strategies for affecting the folding of peptoid constructs.