The application of poly-Si/SiOx contacts as passivated top/rear contacts in Si solar cells

A critical review is presented of the theories proposed in the literature to explain the current gain enhancement of polysilicon emitter bipolar transistors. From these theories a simplified analytical formulation is chosen which models the blocking properties of the interface, including tunneling through the interfacial oxide, reduced grain boundary mobility at the polysilicon/silicon interface, and the potential barrier created by segregated dopant, which can all give rise to an enhanced current gain. Also modeled are the mechanisms which limit the extent of any gain enhancement, such as recombination in the single-crystal emitter, in the bulk of the polysilicon, and at the polysilicon/silicon interface. This model is then applied in an original manner to a selection of experimental data in an effort to identify the dominant current gain mechanisms in polysilicon emitter transistors as a function of a given set of fabrication conditions. >

Polysilicon emitters for bipolar transistors: a review and re-evaluation of theory and experiment

Phosphorus-diffused polysilicon contacts for solar cells

The physics of minority-carrier injection into polysilicon-contacted emitters has been studied through a series of experiments correlating the base current of the transistor to the structure of the polysilicon/single-crystal silicon interface. Most of the relevant material and processing parameters have been examined. In addition, a novel approach has been taken in the modeling of transport in these emitters to quantify the minority-carrier blocking properties of the polysilicon contacts. Experimental results show that extremely low values of base current can be obtained for devices etched in HF prior to the polysilicon deposition, i.e., devices with only a remnant "native" oxide layer at the polysilicon/single-crystal silicon interface. For these devices, the base current is mainly determined by the recombination and blocking of minority carriers at the polysilicon/monosilicon interface. A number of competing mechanisms exist in several domains of doping, temperature, and time which influence the properties of this interface. One of these mechanisms is the blocking of minority carriers by the native oxide layer itself. The uniformity and, consequently, the blocking characteristics of this layer were found to be strongly affected by the polysilicon doping level and thermal treatment.

Physics, technology, and modeling of polysilicon emitter contacts for VLSI bipolar transistors

Ion implantation of boron into undoped polysilicon is utilized. The main goals are to characterize the diffusion of implanted boron from polysilicon, and to correlate the diffusion behavior with the electrical properties of shallow ( >

Investigation of boron diffusion in polysilicon and its application to the design of p-n-p polysilicon emitter bipolar transistors with shallow emitter junctions

This paper presents the results of an experimental study designed to explore both qualitatively and quantitatively the mechanism of the improved current gain in bipolar transistors with polysilicon emitter contacts. Polysilicon contacts were deposited and heat treated at different conditions. The electrical properties Were measured using p-n junction test structures that are much more sensitive to the contact properties than are bipolar transistors. A simple phenomenological model was used to correlate, the structural properties with electrical measurements. Possible transport mechanisms are examined and estimates are made about upper bounds on transport parameters in the principal regions of the devices. The main conclusion of this study is that the minority-carrier transport in the polycrystalline silicon is dominated by a highly disordered layer at the polysilicon-monosilicon interface characterized by very low minority-carrier mobility. The effective recombination velocity at the n+polysilicon-n+monosilicon interface was found to be a strong function of fabrication conditions. The results indicate that the recombination velocity can be much smaller than 104cm/s.

R.D. Isaac

Papers

Experimental study of the minority-carrier transport at the polysilicon—monosilicon interface

R.D. Isaac

Papers

Experimental study of the minority-carrier transport at the polysilicon&#8212;monosilicon interface

Experimental study of the minority-carrier transport at the polysilicon—monosilicon interface