Single-crystal silicon is being increasingly employed in a variety of new commercial products not because of its well-established electronic properties, but rather because of its excellent mechanical properties. In addition, recent trends in the engineering literature indicate a growing interest in the use of silicon as a mechanical material with the ultimate goal of developing a broad range of inexpensive, batch-fabricated, high-performance sensors and transducers which are easily interfaced with the rapidly proliferating microprocessor. This review describes the advantages of employing silicon as a mechanical material, the relevant mechanical characteristics of silicon, and the processing techniques which are specific to micromechanical structures. Finally, the potentials of this new technology are illustrated by numerous detailed examples from the literature. It is clear that silicon will continue to be aggressively exploited in a wide variety of mechanical applications complementary to its traditional role as an electronic material. Furthermore, these multidisciplinary uses of silicon will significantly alter the way we think about all types of miniature mechanical devices and components.

Silicon as a mechanical material

Extending the methodology of X-ray crystallography to allow imaging of micrometre-sized non-crystalline specimens

The authors review the development of extended x-ray absorption fine structure (EXAFS) within the last decade. Advances in experimental techniques have been largely stimulated by the availability of synchrotron radiation. The theory of EXAFS has also matured to the point where quantitative comparison with experiments can be made. The authors review in some detail the analysis of EXAFS data, starting from the treatment of raw data to the extraction of distances and amplitude information, and they also discuss selected examples of applications of EXAFS chosen to illustrate both the strength and limitations of EXAFS as a structural tool.

Extended x-ray absorption fine structure—its strengths and limitations as a structural tool

The sensitivity of oceanic thermohaline circulation to freshwater perturbations is a critical issue for understanding abrupt climate change1 Abrupt climate fluctuations that occurred during both Holocene and Late Pleistocene times have been linked to changes in ocean circulation2,3,4,5,6, but their causes remain uncertain One of the largest such events in the Holocene occurred between 8,400 and 8,000 calendar years ago2,7,8 (7,650–7,200 14C years ago), when the temperature dropped by 4–8 °C in central Greenland2 and 15–3 °C at marine4,7 and terrestrial7,8 sites around the northeastern North Atlantic Ocean The pattern of cooling implies that heat transfer from the ocean to the atmosphere was reduced in the North Atlantic Here we argue that this cooling event was forced by a massive outflow of fresh water from the Hudson Strait This conclusion is based on our estimates of the marine 14C reservoir for Hudson Bay which, in combination with other regional data, indicate that the glacial lakes Agassiz and Ojibway9,10,11,12, (originally dammed by a remnant of the Laurentide ice sheet) drained catastrophically ∼8,470 calendar years ago; this would have released >1014 m3 of fresh water into the Labrador Sea This finding supports the hypothesis2,7,8 that a sudden increase in freshwater flux from the waning Laurentide ice sheet reduced sea surface salinity and altered ocean circulation, thereby initiating the most abrupt and widespread cold event to have occurred in the past 10,000 years

Forcing of the cold event of 8,200 years ago by catastrophic drainage of Laurentide lakes

Transmission microscopy of unmodified biological materials. Comparative radiation dosages with electrons and ultrasoft X-ray photons

Calculations are presented which indicate an extensive suboptical region in the microscopy of biological materials in their natural state which is accessible to ultrasoft x-ray transmission microscopy. Throughout most of the region, radiation dosage levels to the specimen are lower than in electron microscopy.

https://science.sciencemag.org/content/sci/196/4296/1339.full.pdf

Potential Operating Region for Ultrasoft X-ray Microscopy of Biological Materials

X-ray holography offers the possibility of three-dimensional microscopy with resolution higher than that of the light microscope and with contrast based on x-ray edges. In principle, the method is especially advantageous for biological samples if x-rays in the wavelength region between the carbon and oxygen K edges are used. However, until now the achieved resolution has not exceeded that of the light microscope because of the poor coherence properties of the x-ray sources and the low resolution of the detectors that were available. With a recently developed x-ray source based on an undulator on an electron storage ring, and high resolution x-ray resist, a hologram has been recorded at about 400-angstrom resolution. The experiment utilized x-rays with wavelengths of 24.7 angstroms and required a 1-hour exposure of the pancreatic zymogen granules under study.

/pdf/x-ray-holograms-at-improved-resolution-a-study-of-zymogen-4ipocdu9xw.pdf

X-ray holograms at improved resolution: a study of zymogen granules.

X-ray micrographs of biological materials have been obtained with a resolution better than 100 angstroms by using x-ray resist as the recording medium. A high-resolution scanning electron microscope with a short-focal-length final lens, operating in the "low-loss" mode, is used to make the smallest features in the x-ray replica visible.

https://science.sciencemag.org/content/sci/197/4300/259.full.pdf

High-resolution soft x-ray microscopy.

A 100-nanosecond pulse of long-wavelength x-rays was used to produce high-resolution stop-motion images of living human platelets. Although some aspects of the structure conform to those seen in dehydrated specimens, novel features are apparent. The technique should permit detailed stop-motion examination of the interaction of platelets with their surrounding medium as well as exploration of the phagocytic and secretory activities of a wide variety of other cells.

https://science.sciencemag.org/content/sci/227/4682/63.full.pdf

Ralph Feder

Papers

Transmission microscopy of unmodified biological materials. Comparative radiation dosages with electrons and ultrasoft X-ray photons

Potential Operating Region for Ultrasoft X-ray Microscopy of Biological Materials

X-ray holograms at improved resolution: a study of zymogen granules.

High-resolution soft x-ray microscopy.

Direct imaging of live human platelets by flash x-ray microscopy.