R
Régine Amardeil
Researcher at University of Burgundy
Publications - 26
Citations - 1143
Régine Amardeil is an academic researcher from University of Burgundy. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 17, co-authored 25 publications receiving 1066 citations. Previous affiliations of Régine Amardeil include Centre national de la recherche scientifique.
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Progress in palladium-based catalytic systems for the sustainable synthesis of annulated heterocycles: a focus on indole backbones.
TL;DR: This critical review clearly indicates that the development of ligand chemistry, mainly phosphines and carbenes, in the last few decades gave a significant impetus to powerful functionalization of indoles at virtually all positions of this ubiquitous backbone.
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Structural diversity in coordination chemistry of tridentate and tetradentate polyphosphines of Group 6 to 10 transition metal complexes
Jean-Cyrille Hierso,Régine Amardeil,Emmanuelle Bentabet,Roland Broussier,Bernard Gautheron,Philippe Meunier,Philippe Kalck +6 more
TL;DR: Tridentate and tetradentate polyphosphines offer a huge variety of coordination modes to transition metals which lead, depending on the metal, to very different structural features in the resulting complexes as mentioned in this paper.
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Catalytic Efficiency of a New Tridentate Ferrocenyl Phosphine Auxiliary: Sonogashira Cross-Coupling Reactions of Alkynes with Aryl Bromides and Chlorides at Low Catalyst Loadings of 10-1 to 10-4 Mol %
Jean-Cyrille Hierso,Aziz Fihri,Régine Amardeil,Philippe Meunier,Henri Doucet,Maurice Santelli,Vladimir V. Ivanov +6 more
TL;DR: The novel mixed ferrocenyl aryl/alkyl triphosphine is thermally stable and insensitive to air or moisture, and its robustness allows aryL alkynylation at 10(-1) to 10(-4) mol % catalyst loadings with TONs up to 250,000.
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A Palladium−Ferrocenyl Tetraphosphine System as Catalyst for Suzuki Cross-Coupling and Heck Vinylation of Aryl Halides: Dynamic Behavior of the Palladium/Phosphine Species
Jean-Cyrille Hierso,Aziz Fihri,Régine Amardeil,Philippe Meunier,Henri Doucet,Maurice Santelli,Bruno Donnadieu +6 more
TL;DR: In this paper, a new ferrocenyl tetraphosphine 1,1,2,2-tetrakis(diphenylphosphino)-4,4'-di-tert-butylferrocene (called Fc(P) 4 tBu, 1) and [PdCl(η 3 -C 3 H 5 )] 2 has been found to be an active catalyst for the cross-coupling of aryl halides with alkenes.
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“Through-Space” Nuclear Spin−Spin JPP Coupling in Tetraphosphine Ferrocenyl Derivatives: A 31P NMR and X-ray Structure Correlation Study for Coordination Complexes
Jean-Cyrille Hierso,Aziz Fihri,Vladimir V. Ivanov,Bernard Hanquet,Nadine Pirio,Bruno Donnadieu,Bertrand Rebière,Régine Amardeil,Philippe Meunier +8 more
TL;DR: Based on the reported observations, the lone-pair overlap model is extended to "through-space" (31)P( 31)P coupling, and the model is broadened to encompass metal orbital contributions for coordination complexes.