R
Richard P. Matthews
Researcher at Imperial College London
Publications - 22
Citations - 1616
Richard P. Matthews is an academic researcher from Imperial College London. The author has contributed to research in topics: Ionic liquid & Hydrogen bond. The author has an hindex of 13, co-authored 20 publications receiving 1286 citations. Previous affiliations of Richard P. Matthews include University of Cape Town.
Papers
More filters
Journal ArticleDOI
Hydrogen bonding in ionic liquids
TL;DR: Using the applicability and extension of these parameters to describe and quantify the doubly ionic H-bond has been explored, and it is clear that doubly ionsicH-bonds cover the full range of weak through to very strong H- bonds.
Journal ArticleDOI
Doubly ionic hydrogen bond interactions within the choline chloride-urea deep eutectic solvent.
TL;DR: The pairwise interactions of the constituent components of the choline chloride-urea DES are examined and it is found that the covalency of doubly ionic H-bonds can be greater than, or comparable with, neutral and ionic examples.
Journal ArticleDOI
Competitive pi interactions and hydrogen bonding within imidazolium ionic liquids.
TL;DR: It is found that low energy IP-dimers are not necessarily formed from the lowest energy IP conformers, and the sampled range of IP-Dimers exhibits new structural forms that cannot be recovered by examining the ion-pairs alone, moreover the IP- dimers are recovering additional key features of the local liquid structure.
Journal ArticleDOI
Hydrogen bonding in 1-butyl- and 1-ethyl-3-methylimidazolium chloride ionic liquids.
TL;DR: Analyses of the individual atom-atom pair radial distribution functions, and in particular those for C···Cl(-), have revealed that hydrogen bonding to the first methylene or methyl units of the substituent groups is important.
Journal ArticleDOI
Hydrogen bonding and π–π interactions in imidazolium-chloride ionic liquid clusters
TL;DR: Overall it is found that structural fluidity is facilitated by fluctuating hydrogen bond, π(+)-π (+) and anion-π(+) interactions.