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Robert C. Harris

Researcher at University of Leicester

Publications -  39
Citations -  3052

Robert C. Harris is an academic researcher from University of Leicester. The author has contributed to research in topics: Deep eutectic solvent & Ionic liquid. The author has an hindex of 20, co-authored 35 publications receiving 2464 citations.

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Glycerol eutectics as sustainable solvent systems

TL;DR: The physical properties of choline chloride mixtures with glycerol are quantified and it is shown that eutectic mixtures can circumvent some of the difficulties of using Glycerol as a solvent viz. high viscosity and high melting point.
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Application of hole theory to define ionic liquids by their transport properties.

TL;DR: The conductivity, viscosity, density, and surface tension of a number of glycolic mixtures with choline chloride are measured and it is proposed that the composition at which the measured conductivity matches the theoretical value is the point at which hole mobility becomes the dominant mechanism for charge mobility.
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Molecular motion and ion diffusion in choline chloride based deep eutectic solvents studied by 1H pulsed field gradient NMR spectroscopy

TL;DR: The first pulsed field gradient nuclear magnetic resonance (PFG-NMR) study of DESs found the diffusion mechanism was found to be the same as for ionic liquids with discrete anions, which highlights that the molecular structure of the hydrogen bond donor can greatly affect the mobility of the whole system.
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Extraction of glycerol from biodiesel into a eutectic based ionic liquid

TL;DR: A Lewis basic mixture of quaternary ammonium salts with glycerol has been used to extract excess glycerols from biodiesel formed from the reaction of triglycerides with ethanol in the presence of KOH as discussed by the authors.
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Molecular and ionic diffusion in aqueous – deep eutectic solvent mixtures: probing inter-molecular interactions using PFG NMR

TL;DR: The results reveal that Reline and Glyceline form mixtures that are inhomogeneous at a microscopic level despite the hydrophilicity of the salt and HBD, showing that PFG NMR is a powerful tool to elucidate both molecular dynamics and inter-molecular interactions in complex liquid mixtures, such as the aqueous DES mixtures.