R
Roberto Margarita
Researcher at Sapienza University of Rome
Publications - 35
Citations - 1155
Roberto Margarita is an academic researcher from Sapienza University of Rome. The author has contributed to research in topics: Hypervalent molecule & Reagent. The author has an hindex of 12, co-authored 35 publications receiving 1110 citations. Previous affiliations of Roberto Margarita include Bristol-Myers Squibb & Université de Montréal.
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A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds
TL;DR: Catalytic amounts of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) are used in combination with [bis(acetoxy)iodo]benzene (BAIB) as a stoichiometric oxidant in the conversion of primary and secondary alcohols to carbonyl compounds.
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Layered zirconium phosphate and phosphonate as heterogeneous catalyst in the preparation of pyrroles
TL;DR: Pyrroles may be prepared by condensation of alkyl and aryl amines and 1,4-diketones (Paal-Knorr reaction) under potassium exchanged layered Zirconium phosphate and zirconiam sulfophenyl phosphonate catalyst in solvent free conditions as discussed by the authors.
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Total Synthesis and Structural Confirmation of the Marine Natural Product Dysinosin A: A Novel Inhibitor of Thrombin and Factor VIIa
Stephen Hanessian,Roberto Margarita,Adrian Hall,Shawn Johnstone,Martin Tremblay,Luca Parlanti +5 more
TL;DR: The structure and absolute configuration of the marine antithrombotic product dysinosin A was confirmed by total synthesis by disconnections to three subunits, of which two were synthesized from the readily available l-glutamic acid, d-leucine, and d-mannitol.
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Radical additions to olefins in the presence of iodobenzenediacetate: an easy route to alkyl dithiocyanates
TL;DR: In this article, a new application of iodobenzenediacetate (IBDA) was described, which is able to oxidize thiocyanate anion to the corresponding radical.
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The binary reagent PhI(OAc)2-Mg(CIO4)2:a SET induced ring enlargement of furan derivatives into pyranones
TL;DR: The binary reagent PhI(OAc) 2 -Mg(CIO 4 ) 2 is very efficient for a high conversion of (2-furyl)-1-alcohols into pyranones.