R
Rolfe H. Herber
Researcher at Hebrew University of Jerusalem
Publications - 171
Citations - 3879
Rolfe H. Herber is an academic researcher from Hebrew University of Jerusalem. The author has contributed to research in topics: Mössbauer spectroscopy & Tin. The author has an hindex of 33, co-authored 171 publications receiving 3672 citations. Previous affiliations of Rolfe H. Herber include The Racah Institute of Physics & Texas A&M University.
Papers
More filters
Journal ArticleDOI
Origin of Polychromism of Cis Square-Planar Platinum(II) Complexes: Comparison of Two Forms of [Pt(2,2'-bpy)(Cl2]
TL;DR: In this article, single crystals of the yellow form of [Pt(2,2'-bpy)(Cl) 2 ] have been prepared, and the crystal structure is compared to that of the Pd(II) homologue reported earlier.
Journal ArticleDOI
Systematics of Mössbauer Isomer Shifts of Organo‐Tin Compounds
TL;DR: The linear relationship between isomer shift and ligand electronegativity suggested by Goldanskii for compounds of the type SnX4 has been extended to organo-tin compounds with mixed ligands.
Journal ArticleDOI
Electron-transfer processes in metal-free tetraferrocenylporphyrin. Understanding internal interactions to access mixed-valence States potentially useful for quantum cellular automata.
Victor N. Nemykin,Gregory T. Rohde,Christopher D. Barrett,Ryan G. Hadt,Claudia Bizzarri,Pierluca Galloni,Barbara Floris,Israel Nowik,Rolfe H. Herber,Andrea Giacomo Marrani,Robertino Zanoni,Nikolay M. Loim +11 more
TL;DR: The chemical oxidation of H(2)TFcP was tested using a variety of oxidants which resulted in formation of mixed-valence compounds, which were characterized by UV-vis-NIR, MCD, IR, Mossbauer, and XPS spectroscopy.
Journal ArticleDOI
Fe57 Mössbauer Effect in Ferrocene Derivatives
G. K. Wertheim,Rolfe H. Herber +1 more
TL;DR: The hyperfine structure in the Mossbauer spectrum of Fe57 in ferrocene and in related compounds shows that the bonding of the iron atom is not affected by ring substitution.
Journal ArticleDOI
C5H4 ? BR2 Bending in Ferrocenylboranes: A Delocalized Through‐Space Interaction Between Iron and Boron
Matthias Scheibitz,Michael Bolte,Jan W. Bats,H.-Wolfram Lerner,Israel Nowik,Rolfe H. Herber,Andreas Krapp,Matthias Lein,Max C. Holthausen,Matthias Wagner +9 more
TL;DR: A comparison of the molecular structures of mono-, di- and tetraborylated ferrocenes revealed the boryl substituent(s) to be bent out of the Cp ring plane towards the iron center, and a substantial anodic shift in the oxidation potential of the central iron atom upon introduction of BMe(2) substituents.