B
Barbara Floris
Researcher at University of Rome Tor Vergata
Publications - 99
Citations - 2102
Barbara Floris is an academic researcher from University of Rome Tor Vergata. The author has contributed to research in topics: Catalysis & Ionic liquid. The author has an hindex of 24, co-authored 99 publications receiving 1911 citations. Previous affiliations of Barbara Floris include Sapienza University of Rome.
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Journal ArticleDOI
Mechanistic aspects of vanadium catalysed oxidations with peroxides
TL;DR: A selection of recent achievements concerning the reaction mechanisms in the vanadium catalysed oxidation and bromination reactions with peroxides can be found in this paper, however, no clear-cut evidence of nucleophilic reactivity of vanadium peroxo complexes has been obtained.
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Electron-transfer processes in metal-free tetraferrocenylporphyrin. Understanding internal interactions to access mixed-valence States potentially useful for quantum cellular automata.
Victor N. Nemykin,Gregory T. Rohde,Christopher D. Barrett,Ryan G. Hadt,Claudia Bizzarri,Pierluca Galloni,Barbara Floris,Israel Nowik,Rolfe H. Herber,Andrea Giacomo Marrani,Robertino Zanoni,Nikolay M. Loim +11 more
TL;DR: The chemical oxidation of H(2)TFcP was tested using a variety of oxidants which resulted in formation of mixed-valence compounds, which were characterized by UV-vis-NIR, MCD, IR, Mossbauer, and XPS spectroscopy.
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Vanadium catalyzed oxidation with hydrogen peroxide
Valeria Conte,Barbara Floris +1 more
TL;DR: In this article, structural and mechanistic studies concerning the behavior of peroxovanadates toward a number of different substrates are collected, in addition, interesting synthetic results obtained with the use of ionic liquids as reaction media are also presented.
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Vanadium and molybdenum peroxides: synthesis and catalytic activity in oxidation reactions.
Valeria Conte,Barbara Floris +1 more
TL;DR: The most recent achievements concerning the synthesis and characterization, as well as the key aspects of reactivity, of V(V) and Mo(VI) peroxo complexes have been collected here.
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Long-range electronic communication in free-base meso-poly(ferrocenyl)-containing porphyrins.
Victor N. Nemykin,Gregory T. Rohde,Christopher D. Barrett,Ryan G. Hadt,Jared R. Sabin,Giacomo Reina,Giacomo Reina,Pierluca Galloni,Barbara Floris +8 more
TL;DR: Analysis of intervalence charge-transfer bands observed in the NIR region for all mixed-valence complexes suggests electron localization and thus class II behavior in the Robin-Day classification.