R
Rubén Vicente
Researcher at University of Oviedo
Publications - 104
Citations - 7707
Rubén Vicente is an academic researcher from University of Oviedo. The author has contributed to research in topics: Catalysis & Carbene. The author has an hindex of 35, co-authored 101 publications receiving 7144 citations. Previous affiliations of Rubén Vicente include Complutense University of Madrid & University of Göttingen.
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Transition-metal-catalyzed direct arylation of (hetero)arenes by C-H bond cleavage.
TL;DR: P palladium and ruthenium catalysts have been described that enable the direct arylation of (hetero)arenes with challenging coupling partners--including electrophilic aryl chlorides and tosylates as well as simple arenes in cross-dehydrogenative arylations.
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Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C-H-Bindungsbruch
TL;DR: In this paper, Palladium-and Ruthenium-katalysatoren have been beschrieben, welche die direkte Arylierung von (Hetero)arenen mit anspruchsvollen Reaktionspartnern ermoglichen; hierzu gehoren elektrophile Arylchloride und -tosylate oder auch einfache Arene in gekreuzten dehydrierenden ADC.
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Assisted ruthenium-catalyzed C-H bond activation: carboxylic acids as cocatalysts for generally applicable direct arylations in apolar solvents.
TL;DR: Catalytic amounts of aromatic carboxylic acid MesCO H enabled efficient ruthenium-catalyzed direct arylations in apolar solvents with unparalleled broad scope via a concerted deprotonation-metalation mechanism.
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Recent advances in indole syntheses: New routes for a classic target
TL;DR: Indoles are the most abundant heterocycles in biologically active natural products, pharmaceuticals, agrochemicals, and are relevant substructures in functional materials.
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Copper-catalyzed "click" reaction/direct arylation sequence: modular syntheses of 1,2,3-triazoles.
TL;DR: Inexpensive copper catalysts enabled modular one-pot multicomponent syntheses of fully decorated triazoles through a sustainable "click" reaction/direct arylation sequence.