R
Ruofei Cheng
Researcher at Chinese Academy of Sciences
Publications - 5
Citations - 235
Ruofei Cheng is an academic researcher from Chinese Academy of Sciences. The author has contributed to research in topics: Carborane & Chirality (chemistry). The author has an hindex of 4, co-authored 5 publications receiving 173 citations.
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Journal ArticleDOI
Iridium-catalysed regioselective borylation of carboranes via direct B-H activation.
TL;DR: A very efficient iridium-catalysed borylation of cage B(3,6)–H bonds of o-carboranes with excellent yields and regioselectivity using bis(pinacolato)diboron (B2pin2) as a reagent is reported.
Journal ArticleDOI
Enantioselective Synthesis of Chiral-at-Cage o-Carboranes via Pd-Catalyzed Asymmetric B-H Substitution.
Ruofei Cheng,Bowen Li,Jie Wu,Jie Zhang,Zaozao Qiu,Wenjun Tang,Shu-Li You,Yong Tang,Zuowei Xie,Zuowei Xie +9 more
TL;DR: This work reports an efficient method to achieve chiral-at-cage arylation of o-carboranes with high regio- and enantioselectivities by a strategy of palladium-catalyzed asymmetric intramolecular B-H arieslation and cyclization.
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Iridium-Catalyzed Regioselective B(3)-Alkenylation/B(3,6)-Dialkenylation of o-Carboranes by Direct B-H Activation
TL;DR: Iridium catalyzed formal alkyne hydroboration with cage B-H of o -carborane has been achieved, leading to the controlled synthesis of a series of olefinic units in high yields with excellent regio and very good cis-trans selectivity.
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Facile Synthesis of N-Carboranyl Amines through an ortho-Carboryne Intermediate
TL;DR: This work has proposed the first general and efficient method for the synthesis of 1-NR(1) R(2) -o-carboranes, compatible with a broad substrate scope from primary to secondary, alkyl to aryl amines.