S
Salvador B. Muñoz
Researcher at Indiana University
Publications - 6
Citations - 277
Salvador B. Muñoz is an academic researcher from Indiana University. The author has contributed to research in topics: Carbene & Ligand. The author has an hindex of 6, co-authored 6 publications receiving 225 citations. Previous affiliations of Salvador B. Muñoz include New Mexico State University.
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Journal ArticleDOI
Ligand Modification Transforms a Catalase Mimic into a Water Oxidation Catalyst
TL;DR: Control experiments are in support of a homogeneous molecular catalyst and preliminary mechanistic studies suggest that the catalyst is mononuclear, which has implications for the design of new manganese-based water oxidation catalysts.
Journal ArticleDOI
Styrene Aziridination by Iron(IV) Nitrides
Salvador B. Muñoz,Wei-Tsung Lee,Diane A. Dickie,Jeremiah J. Scepaniak,Deepak Subedi,Maren Pink,Michael D. Johnson,Jeremy M. Smith +7 more
TL;DR: Thermolysis of the iron(IV) nitride complex with styrene leads to formation of the high-spin iron(II) aziridino complex [PhB(tBuIm)3Fe-N(CH2CHPh)], which closes a synthetic cycle for styrene azirdination by a nitridecomplex.
Journal ArticleDOI
Tris(carbene)borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene, and 1,3,4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO}10 complexes.
Salvador B. Muñoz,Wallace K. Foster,Hsiu-Jung Lin,Charles G. Margarit,Diane A. Dickie,Jeremy M. Smith +5 more
TL;DR: There is a large variation in ν(NO), suggesting these tris(carbene)borate ligands to have a wide range of donor strengths while maintaining a consistent ligand topology.
Journal ArticleDOI
Reaction of an iron(IV) nitrido complex with cyclohexadienes: cycloaddition and hydrogen-atom abstraction.
Wei-Tsung Lee,Ruth A. Juarez,Jeremiah J. Scepaniak,Salvador B. Muñoz,Diane A. Dickie,Haobin Wang,Jeremy M. Smith +6 more
TL;DR: The proposed reaction mechanism, supported by electronic structure calculations, involves hydrogen-atom abstraction from 1,4-cyclohexadiene to provide the cyclohexadienyl radical, leading to formation of the pyrrolide product.
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Arrested α-hydride migration activates a phosphido ligand for C-H insertion.
TL;DR: An arrested α-hydride migration mechanism suggests increased nucleophilicity of the phosphorus atom facilitates [PPh] group transfer reactivity at high spin iron(ii) phosphido complexes.