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Shobhana Krishnaswamy

Researcher at Indian Institute of Technology Madras

Publications -  24
Citations -  265

Shobhana Krishnaswamy is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Crystal structure & Crystallization. The author has an hindex of 9, co-authored 22 publications receiving 190 citations. Previous affiliations of Shobhana Krishnaswamy include Council of Scientific and Industrial Research & National Chemical Laboratory.

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Journal ArticleDOI

Self-assembled conjoined-cages.

TL;DR: Modular construction of multi-3D-cavity cages featuring one, two or three units of a [Pd2L4] entity conjoined with a[Pd3L6] core is reported.
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Reversible Mechanical Interlocking of D-Shaped Molecular Karabiners bearing Coordination-Bond Loaded Gates: Route to Self-Assembled [2]Catenanes

TL;DR: Crystal structures of the macrocycle [Pd2 (tmeda)2 (L1)(L2)](PF6 )4, 4 b'', and the catenane [PD2 (bpy)2 [L1](L2]2 (NO3 )8, 5 c, provide unequivocal support for the proposed molecular architectures.
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Self-Assembled Molecular Squares as Supramolecular Tectons

TL;DR: In this paper, the authors showed that AgOTs to each mixture of square and triangle led to a shift in the equilibrium, resulting in the disappearance of the triangles and exclusive formation of the corresponding squares.
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Low-Symmetry Self-Assembled Coordination Complexes with Exclusive Diastereoselectivity: Experimental and Computational Studies

TL;DR: A pyridine/aniline appended unsymmetrical bidentate ligand N-(4-aminobenzyl)phenyl)nicotinamide, investigated in this work has two well-separated coordination sites that produced the corresponding Pd2L'2Lun2 and extremely rare Pd 2Lun4 type self-assembled binuclear complexes, respectively.
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cis-Protected palladium(II) based binuclear complexes as tectons in crystal engineering and the imperative role of the cis-protecting agent

TL;DR: A survey of the Cambridge Structural Database (CSD) for crystal structures of binuclear coordination complexes, formed by the combination of suitable ligand(s) and Pd(II) centres which are protected in a cis fashion by 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), tetramethylethylenediamine (tmeda) or ethylened amine (en), was carried out.