Geophysical, petrological, and geochemical data provide important clues about the composition of the deep continental crust. On the basis of seismic refraction data, we divide the crust into type sections associated with different tectonic provinces. Each shows a three-layer crust consisting of upper, middle, and lower crust, in which P wave velocities increase progressively with depth. There is large variation in average P wave velocity of the lower crust between different type sections, but in general, lower crustal velocities are high (>6.9 km s−1) and average middle crustal velocities range between 6.3 and 6.7 km s−1. Heat-producing elements decrease with depth in the crust owing to their depletion in felsic rocks caused by granulite facies metamorphism and an increase in the proportion of mafic rocks with depth. Studies of crustal cross sections show that in Archean regions, 50–85% of the heat flowing from the surface of the Earth is generated within the crust. Granulite terrains that experienced isobaric cooling are representative of middle or lower crust and have higher proportions of mafic rocks than do granulite terrains that experienced isothermal decompression. The latter are probably not representative of the deep crust but are merely upper crustal rocks that have been through an orogenic cycle. Granulite xenoliths provide some of the deepest samples of the continental crust and are composed largely of mafic rock types. Ultrasonic velocity measurements for a wide variety of deep crustal rocks provide a link between crustal velocity and lithology. Meta-igneous felsic, intermediate and mafic granulite, and amphibolite facies rocks are distinguishable on the basis of P and S wave velocities, but metamorphosed shales (metapelites) have velocities that overlap the complete velocity range displayed by the meta-igneous lithologies. The high heat production of metapelites, coupled with their generally limited volumetric extent in granulite terrains and xenoliths, suggests they constitute only a small proportion of the lower crust. Using average P wave velocities derived from the crustal type sections, the estimated areal extent of each type of crust, and the average compositions of different types of granulites, we estimate the average lower and middle crust composition. The lower crust is composed of rocks in the granulite facies and is lithologically heterogeneous. Its average composition is mafic, approaching that of a primitive mantle-derived basalt, but it may range to intermediate bulk compositions in some regions. The middle crust is composed of rocks in the amphibolite facies and is intermediate in bulk composition, containing significant K, Th, and U contents. Average continental crust is intermediate in composition and contains a significant proportion of the bulk silicate Earth's incompatible trace element budget (35–55% of Rb, Ba, K, Pb, Th, and U).

Nature and composition of the continental crust: A lower crustal perspective

The science of the total environment

The validity of the cubic law for laminar flow of fluids through open fractures consisting of parallel planar plates has been established by others over a wide range of conditions with apertures ranging down to a minimum of 0.2 µm. The law may be given in simplified form by Q/Δh = C(2b)3, where Q is the flow rate, Δh is the difference in hydraulic head, C is a constant that depends on the flow geometry and fluid properties, and 2b is the fracture aperture. The validity of this law for flow in a closed fracture where the surfaces are in contact and the aperture is being decreased under stress has been investigated at room temperature by using homogeneous samples of granite, basalt, and marble. Tension fractures were artificially induced, and the laboratory setup used radial as well as straight flow geometries. Apertures ranged from 250 down to 4µm, which was the minimum size that could be attained under a normal stress of 20 MPa. The cubic law was found to be valid whether the fracture surfaces were held open or were being closed under stress, and the results are not dependent on rock type. Permeability was uniquely defined by fracture aperture and was independent of the stress history used in these investigations. The effects of deviations from the ideal parallel plate concept only cause an apparent reduction in flow and may be incorporated into the cubic law by replacing C by C/ƒ. The factor ƒ varied from 1.04 to 1.65 in these investigations. The model of a fracture that is being closed under normal stress is visualized as being controlled by the strength of the asperities that are in contact. These contact areas are able to withstand significant stresses while maintaining space for fluids to continue to flow as the fracture aperture decreases. The controlling factor is the magnitude of the aperture, and since flow depends on (2b)3, a slight change in aperture evidently can easily dominate any other change in the geometry of the flow field. Thus one does not see any noticeable shift in the correlations of our experimental results in passing from a condition where the fracture surfaces were held open to one where the surfaces were being closed under stress.

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VALIDITY OF CUBIC LAW FOR FLUID FLOW IN A DEFORMABLE ROCK FRACTURE - eScholarship

Geological atlas of western and central Europe

The thermal thickness of Precambrian lithosphere is modeled and compared with estimates from seismic tomography and xenolith data. We use the steady state thermal conductivity equation with the same geothermal constraints for all of the Precambrian cratons (except Antarctica) to calculate the temperature distribution in the stable continental lithosphere. The modeling is based on the global compilation of heat flow data by Pollack et al. [1993] and more recent data. The depth distribution of heat-producing elements is estimated using regional models for ∼300 blocks with sizes varying from 1°×1° to about 5°×5° in latitude and longitude and is constrained by laboratory, seismic and petrologic data and, where applicable, empirical heat flow/heat production relationships. Maps of the lateral temperature distribution at depths 50, 100, and 150 km are presented for all continents except Antarctica. The thermal thickness of the lithosphere is calculated assuming a conductive layer overlying the mantle with an adiabat of 1300°C. The Archean and early Proterozoic lithosphere is found to have two typical thicknesses, 200–220 km and 300–350 km. In general, thin (∼220 km) roots are found for Archean and early Proterozoic cratons in the Southern Hemisphere (South Africa, Western Australia, South America, and India) and thicker (>300 km) roots are found in the Northern Hemisphere (Baltic Shield, Siberian Platform, West Africa, and possibly the Canadian Shield). We find that the thickness of continental lithosphere generally decreases with age from >200 km beneath Archean cratons to intermediate values of 200±50 km in early Proterozoic lithosphere, to about 140±50 km in middle and late Proterozoic cratons. Using known crustal thickness, our calculated geotherms, and assuming that isostatic balance is achieved at the base of the lithosphere, we find that Archean and early Proterozoic mantle lithosphere is 1.5% less dense (chemically depleted) than the underlying asthenosphere, while middle and late Proterozoic subcrustal lithosphere should be depleted by ∼0.6–0.7%. Our results suggest three contrasting stages of lithosphere formation at the following ages: >2.5 Ga, 2.5–1.8 Ga, and <1.8 Ga. Ages of komatiites, greenstone belts, and giant dike swarms broadly define similar stages and apparently reflect secular changes in mantle temperature and, possibly, convection patterns.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2000JB900439

Thermal thickness and evolution of Precambrian lithosphere: A global study

Marbles as building stones as well as in their natural environments show complex weathering phenomena. The most important damage scenario is based on the highly anisotropic thermal expansion coefficient α of calcite, i.e. extreme expansion parallel and contraction normal to the crystallographic c-axis. Therefore, the rock fabric and especially the lattice-preferred orientation (texture) of calcite and/or dolomite as the predominant mineral phases in marbles have a significant influence on the mechanical weathering. The textures of marbles from five different locations vary from a more or less perfect prolate to moderate oblate shape of the [006] pole figure tensor. Accordingly, the texture-derived bulk thermal dilatation anisotropy covers a broad range from –0.048 to 0.680. The modelled thermal dilatations correlate with those obtained from experimental measurements. The difference in magnitude is basically explained by the microcrack fabrics which was not considered in the computations. All samples show a deterioration due to thermal treatment regardless of the strength of texture. The directional dependence of (a) the total magnitude of the thermal dilatation coefficient and (b) of the residual strain is highest in marbles with a strong texture, whereas the Carrara marble with a weak texture exhibits a uniform crack formation. The progressive loss of cohesion along grain boundaries due to dilatancy may serve as an example for the initial stage of physical weathering.

Physical weathering of marbles caused by anisotropic thermal expansion

The weathering of historical buildings and, indeed, of monuments and sculptures of natural stone is a problem that has been encountered for hundreds of years. However, a dramatic increase in deterioration in the structure of our built heritage has been observed during the past century. To understand the complex interaction that the stone in a building suffers with its near environment (the building) and the macro environment (the local climate and atmospheric conditions) requires an interdisciplinary approach and the application of many different theoretical, experimental and empirical resources provided by the geosciences, chemistry, material sciences, biology and construction engineers.

The protection of our architectural heritage has both cultural and historical importance, as well as substantial economic and ecological value. Large sums of money are being spent world-wide on measures for the preservation of monuments and historical buildings. Optimization of damage analysis procedures and damage process controls, as well as the development of monitoring and early warning systems for damage prevention, is needed. The past several decades has seen an unprecedented level of research activity in this area, the results of which are often difficult to access. This volume is intended to provide an integrated approach to the study of the deterioration of geomaterials, making the research available to a wide international audience.

Natural Stone, Weathering Phenomena, Conservation Strategies and Case Studies comprises thirty chapters divided into six sections: weathering of natural building stones; weathering processes; fabric dependence of physical properties; biodeterioration; quality assessment and conservation of stones; and environmental conditions. Review articles are combined with reports on recent progress in the various research fields, authored by a comprehensive team of international contributors. The volume will be of interest to all those involved in the protection of our built heritage, particularly geoscientists, material scientists, construction engineers, architects and stone conservators.

Natural Stone, Weathering Phenomena, Conservation Strategies and Case Studies

A review of the lithostratigraphic units in the Rio de la Plata Craton and of new and previously published geochronological, isotopic and geophysical data is presented. Sm–Nd TDM model ages between 2.6 and 2.2 Ga characterize the Piedra Alta Terrane of this craton. Crystallization ages between 2.2 and 2.1 Ga for the metamorphic protoliths and 2.1–2.0 Ga for the post-orogenic granitoids indicate juvenile crust, followed by a short period of crustal recycling. Cratonization of this terrane occurred during the late Paleoproterozoic. Younger overprinting is not observed, suggesting it had a thick and strong lithosphere in the Neoproterozoic. A similar scenario is indicated for the Tandilia Belt of Argentina. Sm–Nd TDM model ages for the Nico Perez Terrane show two main events of crustal growth (3.0–2.6 and 2.3–1.6 Ga). The crystallization ages on zircon ranges between 3.1 and 0.57 Ga, which is evidence for long-lived crustal reworking. The age for cratonization is still uncertain. In the Taquarembo Block, which is considered the prolongation of the Nico Perez Terrane in southern Brazil, a similar scenario can be observed. These differences together with contrasting geophysical signatures support the redefinition of the Rio de la Plata Craton comprising only the Piedra Alta Terrane and the Tandilia Belt. The Sarandi del Yi Shear Zone is regarded as the eastern margin of this Craton.

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The Río de la Plata Craton: a review of units, boundaries, ages and isotopic signature

Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.

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Physical weathering of building stones induced by freeze–thaw action: a laboratory long-term study

—Seismic anisotropy is often neglected in seismic studies of the earth’s crust. Since anisotropy is a common property of many typically deep crustal rocks, its potential contribution to solving questions of the deep crust is evaluated. The anisotropic seismic velocities obtained from laboratory measurements can be verified by computations based on the elastic constants and on numerical data pertaining to the texture of rock-forming minerals. For typical lower crustal rocks the influence of layering is significantly less important than the influence of rock texture. Surprisingly, most natural lower crustal rocks show a hexagonal type of anisotropy. Maximum anisotropy is observed for rocks with a high content of aligned mica. It seems possible to distinguish between layered intrusives and metasediments on the basis of in situ measurements of anisotropy, which can thus be used to validate different scenarios of crustal evolution.

Siegfried Siegesmund

Papers

Physical weathering of marbles caused by anisotropic thermal expansion

Natural Stone, Weathering Phenomena, Conservation Strategies and Case Studies

The Río de la Plata Craton: a review of units, boundaries, ages and isotopic signature

Physical weathering of building stones induced by freeze–thaw action: a laboratory long-term study

Seismic Velocities and Anisotropy of the Lower Continental Crust: A Review