Stéphane Soriano

Journal ArticleDOI

New Families of Hetero-tri-spin 2p−3d−4f Complexes: Synthesis, Crystal Structures, and Magnetic Properties

- 25 Jun 2014 -

TL;DR: The synthesis, crystal structures, and magnetic behavior of 2p-3d-4f heterospin systems containing the nitroxide radical 4-azido-2,2,6,6-tetramethylpiperidine-1-oxyl radical (N3tempo) are reported.

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Journal ArticleDOI

A chimeric design of heterospin 2p-3d, 2p-4f, and 2p-3d-4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands.

Andrei A. Patrascu, +11 more

- 13 Jun 2017 -

Chemical Communications

TL;DR: End-off bicompartmental ligands bearing a nitronyl-nitroxide arm have been designed for synthesizing various heterospin molecular systems and the magnetic properties of the 2p-4f and2p-3d- 4f complexes have been investigated and rationalized by theoretical calculations.

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Journal ArticleDOI

SMM Behavior Tuned by an Exchange Coupling LEGO Approach for Chimeric Compounds: First 2p-3d-4f Heterotrispin Complexes with Different Metal Ions Bridged by One Aminoxyl Group.

Andrei A. Patrascu, +9 more

- 19 Sep 2019 -

Inorganic Chemistry

TL;DR: The improvement of magnetic properties comes from the synergy of optimal single ions properties and exchange couplings contributions where the CoII-Rad interaction becomes the leading one.

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Journal ArticleDOI

First coordination compounds based on a bis(imino nitroxide) biradical and 4f metal ions: synthesis, crystal structures and magnetic properties

Samira G. Reis, +11 more

- 09 Feb 2016 -

Dalton Transactions

TL;DR: The synthesis, crystal structures and magnetic properties of two families of heterospin complexes containing lanthanide ions and a bis(imino nitroxide) biradical (IPhIN = 1-iodo-3,5-bis(4',4',5',5'-tetramethyl-4,5'-dihydro-1H-imidazole-1'-oxyl)benzene) are reported.

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Journal ArticleDOI

New Synthetic Route toward Heterometallic 3d–3d′ and 3d–4f Single-Molecule Magnets. The First CoII–MnIII Heterometallic Complex

Guilherme P. Guedes, +7 more

- 05 Jul 2013 -

Inorganic Chemistry

TL;DR: Within the four tetranuclear heterometallic complexes, the metal ions bridged by methoxide ligands display a defect-diheterocubane core and show slow relaxation of the magnetization below 4 K.

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Papers

New Families of Hetero-tri-spin 2p−3d−4f Complexes: Synthesis, Crystal Structures, and Magnetic Properties

A chimeric design of heterospin 2p-3d, 2p-4f, and 2p-3d-4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands.

SMM Behavior Tuned by an Exchange Coupling LEGO Approach for Chimeric Compounds: First 2p-3d-4f Heterotrispin Complexes with Different Metal Ions Bridged by One Aminoxyl Group.

First coordination compounds based on a bis(imino nitroxide) biradical and 4f metal ions: synthesis, crystal structures and magnetic properties

New Synthetic Route toward Heterometallic 3d–3d′ and 3d–4f Single-Molecule Magnets. The First CoII–MnIII Heterometallic Complex