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Stephen M. Charsley
Researcher at University of Birmingham
Publications - 6
Citations - 63
Stephen M. Charsley is an academic researcher from University of Birmingham. The author has contributed to research in topics: Crystal structure & Solid solution. The author has an hindex of 5, co-authored 6 publications receiving 63 citations.
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Journal ArticleDOI
Monometallic, homo- and hetero-bimetallic complexes based on redox active tris(3,5-dimethylpyrazolyl)boratomolybdenum and tungsten nitrosyls. Part V.Para-substituent effects on the reduction potentials of arylamide complexes
Najat Al Obaidi,Stephen M. Charsley,W. Hussain,Christopher J. Jones,Jon A. McCleverty,Bryan D. Neaves,Sarah J. Reynolds +6 more
TL;DR: In this paper, the reduction potentials of two series of complexes having the formula [M{HB(3,5-Me2C3N2H)3}(NO)Cl(NHC6H4Z-p)], in which M=Mo and Z=F, Cl, Br, OMe, SMe, CN, CO2Me or NO2, have been prepared.
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Mono- and bi-metallic complexes based on redox-active tris(3,5-dimethylpyrazolyl)borato-molybdenum nitrosyls, part III. (1) Complexes containing meta-substituted benzene- and naphthalenediols or -diamines
TL;DR: In this paper, the interaction between the redox centres in these new species is intermediate (YC6H4Y-m; NHC10H6NH-1,5) or weak (OC10H 6O).
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Monometallic, homo- and hetero-bimetallic complexes based on redox-active tris(3,5-dimethylpyrazolyl)borato molybdenum and tungsten nitrosyls. Part 7. Compounds containing strongly interacting redox centres derived from para-substituted anilines and phenols
Stephen M. Charsley,Chris Jones,Jon A. McCleverty,Bryan D. Neaves,Sarah J. Reynolds,Gianfranco Denti +5 more
TL;DR: In this paper, Chen et al. showed that the redox centres in the bimetallic complexes influence each other strongly, and showed that both the monometallic and bimetal species undergo a one-electron reduction.
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Monometallic, homo- and hetero-bimetallic complexes based on redox-active tris(3,5-dimethylpyrazolyl)borato molybdenum and tungsten nitrosyls. Part 8. Complexes exhibiting weak or intermediate interaction between two redox centres
TL;DR: In this article, the bimetallic complexes of tris(3,5-dimethylpyrazolyl)borate have been prepared and the separation between the redox potentials (ΔE½) varied from 45 mV (negligible interaction between redox centres) to 138mV (weak interaction), depending on the nature of the bridging ligand.
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Synthesis, electrochemistry and spectroelectrochemistry of hydrazido(2-) bridged bimetallic molybdenum species, and the X-ray crystal structure of [Mo{HB(3,5-Me2pz)3}(NO)Cl]2(μ-NHNH) in solid solution
Stephen M. Charsley,Christopher J. Jones,Brian D. Neaves,Roman A. Kresinski,Sean L.W. McWhinnie,Jon A. McCleverty,Lesley J. Yellowlees +6 more
TL;DR: In this article, the authors showed that the mixed-valence species are class III and that all components of the solution contain a near-planar MoNH-NH-NB array and that Cl replacement is isomorphous.