Suchismita Saha

TL;DR: Metal coordination has a manifold of rewards, putting it primo loco in opportunities for putting nanomechanical systems into action, and its strength and dynamics can be properly modulated and fine-tuned by the choice of metal, redox state, and ligand.

TL;DR: Three distinct four-component supramolecular nanorotors, prepared by varying the rotator's structure and keeping all other components constant, exhibit rotational frequencies that differ by almost 2 orders of magnitude, demonstrating the ability of the rotating catalysts to displace the product more efficiently from the active site at higher speed.

TL;DR: Density functional theory computational results suggest that not only coordinative Npy → [Cu(phen)]+ interactions but also dispersive attraction influence the barrier of rotation.

TL;DR: The present work demonstrates the operation of a reversible supramolecular gate, i.e., an ensemble of various components linked by chemical communication, which is triggered by stoichiometric chemical inputs and by obeying the AND truth table delivers a stoichiomet chemical signal.

TL;DR: In this article, the utility of properly designed metal-ligand-binding motifs to furnish self-sorted mononuclear heteroleptic complexes, their sophisticated use in multicomponent supramolecular assemblies and devices and finally even the cutting-edge self sorting of multidevice machinery in action is described.