S
Sushil S. Sakpal
Researcher at National Chemical Laboratory
Publications - 7
Citations - 48
Sushil S. Sakpal is an academic researcher from National Chemical Laboratory. The author has contributed to research in topics: Solvation & Gene. The author has an hindex of 1, co-authored 6 publications receiving 16 citations. Previous affiliations of Sushil S. Sakpal include Academy of Scientific and Innovative Research.
Papers
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Journal ArticleDOI
Hydrocarbon Chain-Length Dependence of Solvation Dynamics in Alcohol-Based Deep Eutectic Solvents: A Two-Dimensional Infrared Spectroscopic Investigation.
Srijan Chatterjee,Deborin Ghosh,Tapas Haldar,Tapas Haldar,Pranab Deb,Pranab Deb,Sushil S. Sakpal,Sushil S. Sakpal,Samadhan H. Deshmukh,Samadhan H. Deshmukh,Somnath M. Kashid,Somnath M. Kashid,Sayan Bagchi,Sayan Bagchi +13 more
TL;DR: Two-dimensional infrared spectroscopy on three alcohol-based DESs by systematically varying the hydrocarbon chain-length reveals that the solvent dynamics slow down monotonically with an increase in the chain- length, and shows a strong correlation with the concomitant rise in the viscosity of DESs.
Journal ArticleDOI
Transition of a Deep Eutectic Solution to Aqueous Solution: A Dynamical Perspective of the Dissolved Solute.
Sushil S. Sakpal,Sushil S. Sakpal,Samadhan H. Deshmukh,Samadhan H. Deshmukh,Srijan Chatterjee,Srijan Chatterjee,Deborin Ghosh,Sayan Bagchi,Sayan Bagchi +8 more
TL;DR: In this paper, a polarization-selective two-dimensional infrared spectroscopy and molecular dynamics simulations of the deep eutectic solvent (DES) nanostructure around the dissolved solute is investigated.
Journal ArticleDOI
Evidence of an n N (amide) → π* Ar Interaction in N -Alkyl- N , N '-diacylhydrazines.
Jugal Kishore Rai Deka,Biswajit Sahariah,Sushil S. Sakpal,Sushil S. Sakpal,Arun Kumar Bar,Sayan Bagchi,Sayan Bagchi,Bani Kanta Sarma +7 more
TL;DR: In this article, an unusual nN(amide) → π*Ar interaction mediated by a hydrazide amide nitrogen atom plays a crucial role in stabilizing their biologically active trans-cis (t-c) rotameric conformations.
Journal ArticleDOI
Stabilization of Azapeptides by Namide···H-Namide Hydrogen Bonds.
Kalpita Baruah,Biswajit Sahariah,Sushil S. Sakpal,Sushil S. Sakpal,Jugal Kishore Rai Deka,Arun Kumar Bar,Sayan Bagchi,Sayan Bagchi,Bani Kanta Sarma +8 more
TL;DR: In this paper, an unusual Namide···H-Namide hydrogen bond (HB) was proposed to stabilize the azapeptide β-turns and showed that this HB endows a stabilization of 1-3 kcal·mol-1 and enforces the transcistrans (t-c-t) and cis-cis-trans (c-c -t) amide bond conformations in azAPEptides and N-methyl-azapeptides.
Book ChapterDOI
Two Dimensional Infrared Spectroscopy: A Structure Sensitive Technique with Ultrafast Time Resolution
Deborin Ghosh,Samadhan H. Deshmukh,Samadhan H. Deshmukh,Srijan Chatterjee,Srijan Chatterjee,Sushil S. Sakpal,Sushil S. Sakpal,Tapas Haldar,Tapas Haldar,Ambuj Dhakad,Somnath M. Kashid,Somnath M. Kashid,Sayan Bagchi,Sayan Bagchi +13 more
TL;DR: A comprehensive review of 2D IR spectroscopy applications can be found in this paper, which provides an in-depth understanding of the applications of this spectroscopic technique in chemistry, materials, and biology.