S
Svetlana V. Amosova
Researcher at Russian Academy of Sciences
Publications - 420
Citations - 2621
Svetlana V. Amosova is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Selenium & Selenide. The author has an hindex of 24, co-authored 407 publications receiving 2311 citations. Previous affiliations of Svetlana V. Amosova include Russian Academy & Saint Petersburg State University.
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Addition of selenium dibromide to divinyl sulfide: spontaneous rearrangement of 2,6-dibromo-1,4-thiaselenane to 5-bromo-2-bromomethyl-1,3-thiaselenolane
TL;DR: In this paper, the synthesis of the selenium heterocycles 1, 2, and 3 based on the addition reaction of Selenium dibromide to divinyl sulfide is described.
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Thia-, Aza-, and Selena[3.3.1]bicyclononane Dichlorides: Rates vs Internal Nucleophile in Anchimeric Assistance
Adrian A. Accurso,So-Hye Cho,Asmarah Amin,Vladimir A. Potapov,Svetlana V. Amosova,M. G. Finn +5 more
TL;DR: Compared substitution rates forulfur-, selenium-, and nitrogen-containing compounds bearing leaving groups in the β-position undergo facile substitution chemistry enabled by anchimeric assistance, showing that the process is controlled by the formation of the high-energy three-membered cationic intermediate.
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A palladium complex with a new hemilabile amino- and sulfur-containing phosphinite ligand as an efficient catalyst for the Heck reaction of aryl bromides with styrene. The effect of the amino group
TL;DR: In this article, a palladium complex with a new hemilabile amino-and sulfur-containing phosphinite ligand has been synthesized and its crystal structure determined, which efficiently catalyses the Heck reaction of aryl bromides with styrene at 130°C after 24h.
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New Palladium Complexes with S‐ or Se‐Containing Schiff‐Base Ligands as Efficient Catalysts for the Suzuki–Miyaura Cross‐Coupling Reaction of Aryl Bromides with Phenylboronic Acid under Aerobic Conditions
Ioannis D. Kostas,Barry R. Steele,Aris Terzis,Svetlana V. Amosova,Alexander V. Martynov,Natalia A. Makhaeva +5 more
TL;DR: In this paper, four palladium chelate complexes with S- or Se-containing substituted salicylaldehyde Schiff base derivatives have been synthesized, which are thermally and air stable and efficiently catalyze the Suzuki-Miyaura crosscoupling of aryl bromides with phenylboronic acid in air.