Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

1,1‘-Binaphthyl Dimers, Oligomers, and Polymers: Molecular Recognition, Asymmetric Catalysis, and New Materials†

2.1.8. Michael Reaction 2245 2.1.9. Others 2247 2.2. Cyclization Reactions 2248 2.2.1. Carbon Diels−Alder Reactions 2248 2.2.2. Aza-Diels−Alder Reactions 2252 2.2.3. Other Hetero-Diels−Alder Reactions 2255 2.2.4. Ionic Diels−Alder Reaction 2256 2.2.5. 1,3-Dipolar Cycloadditions 2256 2.2.6. Other Cycloaddition Reactions 2258 2.2.7. Prins-type Cyclization 2259 2.3. Friedel−Crafts Acylation and Alkylation 2259 2.4. Baylis−Hillman Reaction 2263 2.5. Radical Addition 2264 2.6. Heterocycle Synthesis 2267 2.7. Diazocarbonyl Insertion 2270 3. C−X (X ) N, O, P, Etc.) Bond Formation 2271 3.1. Aromatic Nitration and Sulfonylation 2271 3.2. Michael Reaction 2272 3.3. Glycosylation 2273 3.4. Aziridination 2275 3.5. Diazocarbonyl Insertion 2276 3.6. Ring-Opening Reactions 2277 3.7. Other C−X Bond Formations 2280 4. Oxidation and Reduction 2280 4.1. Oxidation 2280 4.2. Reduction 2281 5. Rearrangement 2283 6. Protection and Deprotection 2285 6.1. Protection 2285 6.2. Deprotection 2288 7. Polymerization 2291 8. Miscellaneous Reactions 2291 9. Lanthanide(II) Triflates in Organic Synthesis 2295 10. Conclusion 2295 11. Acknowledgment 2295 12. References 2295

Rare-earth metal triflates in organic synthesis

BINOL: A Versatile Chiral Reagent

Modified BINOL ligands in asymmetric catalysis.

Asymmetric hetero-Diels-Alder reaction catalyzed by a chiral organoaluminum reagent

Asymmetric ene reaction catalyzed by chiral organoaluminum reagent

A highly effective method for preparation of a variety of sterically hindered chiral binaphthol derivatives has been described which involves the intramolecular 1,3-rearrangement of bis(trialkylsilyl ether) of chiral 3,3′-dibromo-1,1′-bi-2-naphthol with t-BuLi.

Efficient synthesis of sterically hindered chiral binaphthol derivatives.

Asymmetric Hetero-Diels-Alder Reaction Catalyzed by Chiral Organoaluminum Reagent.

Efficient Synthesis of Sterically Hindered Chiral Binaphthol Derivatives.

Tadashi Shirasaka

Papers

Asymmetric hetero-Diels-Alder reaction catalyzed by a chiral organoaluminum reagent

Asymmetric ene reaction catalyzed by chiral organoaluminum reagent

Efficient synthesis of sterically hindered chiral binaphthol derivatives.

Asymmetric Hetero-Diels-Alder Reaction Catalyzed by Chiral Organoaluminum Reagent.

Efficient Synthesis of Sterically Hindered Chiral Binaphthol Derivatives.