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On the nature of

Severe plastic deformation (SPD) is effective in producing bulk ultrafine-grained and nanostructured materials with large densities of lattice defects. This field, also known as NanoSPD, experienced a significant progress within the past two decades. Beside classic SPD methods such as high-pressure torsion, equal-channel angular pressing, accumulative roll-bonding, twist extrusion, and multi-directional forging, various continuous techniques were introduced to produce upscaled samples. Moreover, numerous alloys, glasses, semiconductors, ceramics, polymers, and their composites were processed. The SPD methods were used to synthesize new materials or to stabilize metastable phases with advanced mechanical and functional properties. High strength combined with high ductility, low/room-temperature superplasticity, creep resistance, hydrogen storage, photocatalytic hydrogen production, photocatalytic CO2 conversion, superconductivity, thermoelectric performance, radiation resistance, corrosion resistance, and biocompatibility are some highlighted properties of SPD-processed materials. This article reviews recent advances in the NanoSPD field and provides a brief history regarding its progress from the ancient times to modernity. Abbreviations: ARB: Accumulative Roll-Bonding; BCC: Body-Centered Cubic; DAC: Diamond Anvil Cell; EBSD: Electron Backscatter Diffraction; ECAP: Equal-Channel Angular Pressing (Extrusion); FCC: Face-Centered Cubic; FEM: Finite Element Method; FSP: Friction Stir Processing; HCP: Hexagonal Close-Packed; HPT: High-Pressure Torsion; HPTT: High-Pressure Tube Twisting; MDF: Multi-Directional (-Axial) Forging; NanoSPD: Nanomaterials by Severe Plastic Deformation; SDAC: Shear (Rotational) Diamond Anvil Cell; SEM: Scanning Electron Microscopy; SMAT: Surface Mechanical Attrition Treatment; SPD: Severe Plastic Deformation; TE: Twist Extrusion; TEM: Transmission Electron Microscopy; UFG: Ultrafine Grained GRAPHICAL ABSTRACT IMPACT STATEMENT This article comprehensively reviews recent advances on development of ultrafine-grained and nanostructured materials by severe plastic deformation and provides a brief history regarding the progress of this field.

Nanomaterials by severe plastic deformation: review of historical developments and recent advances

During the last years, the scientific and industrial community has focused on the astonishing properties of Fe-Mn-Al-C steels. These high advanced steels allow high-density reductions about ~15% lighter than conventional steels, high corrosion resistance, high strength (ultimate tensile strength (UTS) ~1 Gpa) and at the same time ductilities above 60%. The increase of the tensile or yield strength and the ductility at the same time is almost a special feature of this kind of new steels, which makes them so interesting for many applications such as in the automotive, armor and mining industry. The control of these properties depends on a complex relationship between the chemical composition of the steel, the test temperature, the external loads and the processing parameters of the steel. This review has been conceived to tried to elucidate these complex relations and gather the most important aspects of Fe-Mn-Al-C steels developed so far.

A General Perspective of Fe-Mn-Al-C Steels

Insight into the recent advances of microwave pretreatment technologies for the conversion of lignocellulosic biomass into sustainable biofuel.

Most of the challenges experienced by many engineering materials originate from the surface which later leads to total failure, hence affecting the resultant mechanical properties and service life. However, these challenges have been addressed thanks to the invention of a novel surface mechanical attrition treatment (SMAT) method which protects the material surface by generating a gradient-structured layer with improved strength and hardness without jeopardizing the ductility. The present work provides a comprehensive literature review on the mechanical properties of materials after SMAT including the hardness, tensile strength and elongation, and residual stress. Firstly, a brief introduction on the different forms of surface nanocrystallization is given to get a better understanding of the SMAT process and its advantages over other forms of surface treatments, and then the grain refinement mechanisms of materials by SMAT from the matrix region (base material) to the nanocrystallized layer are explained. The effects of fatigue, fracture, and wear of materials by the enhanced mechanical properties after SMAT are also discussed in detail. In addition, the various applications of SMAT ranging from automotive, photoelectric conversion, biomedical, diffusion, and 3D-printing of materials are extensively discussed. The prospects and recent research trends in terms of mechanical properties of materials affected by SMAT are then summarized.

https://scholars.cityu.edu.hk/files/71429606/48007958.pdf

Literature review on the mechanical properties of materials after surface mechanical attrition treatment (SMAT)

Torrefaction of biomass materials has received a tremendous attention over the years due to its ability to produce a high-grade solid biofuel with enhanced durability, excellent grindability, higher bulk density and calorific value, and greater energy density, as compared to the original untreated biomass material. It is a mild pyrolysis treatment technology under inert atmosphere which can improve the chemical and physical properties of raw biomass through the elimination of oxygen, reduction of moisture content, and change of chemical compositions. When raw biomass is mildly pyrolyzed in a default-oxygen or N2 atmosphere at moderate temperatures, the properties of raw biomass including low calorific value, hydrogen-carbon ratio, hygroscopicity, and grindability can be significantly enhanced. In the present review, the operating mechanism of different torrefaction processes including wet, dry, and ionic-liquid-assisted torrefaction is analyzed and discussed. More importantly, the reactor design for commercialization purpose, reaction kinetics and mechanism, economics, and sustainability of biomass torrefaction is discussed in detail. This review is extended to the torrefaction of agro-residue biomass since torrefied agro-residue-based pellets can be produced from agro-residues. The various technological applications of biomass torrefaction are also reviewed and the prospects in ensuring the continuous production of high-grade fuels are summarized.

Biomass Torrefaction for the Production of High-Grade Solid Biofuels: a Review

Briquettes are widely used as a renewable energy material for solving the problem of dependency and over-consumption of wood fuel as a source of energy for human use. However, their performance depends on the types and nature of binders used during the preparation and densification process. Most of the performance-related problems such as low yield and energy content can be significantly improved with the use of binders in right proportions. This review discusses the state-of-the-art of fuel briquettes and the influence of binder’s properties on the combustion characteristics, energy content, mechanical durability, and density of fuel briquettes. The compatibility between the binders and the fuel briquettes to obtain a better yield is also discussed with the resulting mechanical and combustion properties. The mechanical durability of fuel briquettes can be improved by reducing the content of lignin, fat, and other extractives in the binder, as well as improving the binder’s variables such as the particle size, texture, and quantity. By using binders mixed with phosphorus-based additives such as Ca(H2PO4)2 and NH4H2PO4, the combustion rate of fuel briquettes can be enhanced and the pollutant emissions during the combustion process can be reduced to the minimum. In addition, the higher the binders’ compacting pressure and processing temperature, the higher the density and energy content per unit volume of fuel briquettes.

Temitope Olumide Olugbade

Papers

Literature review on the mechanical properties of materials after surface mechanical attrition treatment (SMAT)

Biomass Torrefaction for the Production of High-Grade Solid Biofuels: a Review

Influence of binders on combustion properties of biomass briquettes: a recent review.

Effect of multi-interfacial structure on fracture resistance of composite TiSiN/Ag/TiSiN multilayer coating

Enhanced Passivation Layer by Cr Diffusion of 301 Stainless Steel Facilitated by SMAT