T
Teruaki Mukaiyama
Researcher at Kitasato University
Publications - 1072
Citations - 15343
Teruaki Mukaiyama is an academic researcher from Kitasato University. The author has contributed to research in topics: Catalysis & Silylation. The author has an hindex of 52, co-authored 1072 publications receiving 14878 citations. Previous affiliations of Teruaki Mukaiyama include University of Tokyo & Tokyo University of Science.
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Journal ArticleDOI
A CONVENIENT METHOD FOR THE SYNTHESIS OF δ-ALKOXY-β-KETOESTER THE TITANIUM TETRACHLORIDE-ACTIVATED REACTION OF DIKETENE WITH ACETAL
Toshio Izawa,Teruaki Mukaiyama +1 more
TL;DR: In this paper, it was shown that diketene reacts with acetals at −78∼−20°C to afford δ-alkoxy-β-ketoesters in good yields.
Journal ArticleDOI
UNPRECEDENTED GAMMA-SELECTIVE MICHAEL ADDITION OF TIN(II) DIENOLATES TO ACYCLIC α,β-UNSATURATED KETONES
TL;DR: Tin(II) dienolates were found to react exclusively at the gamma carbon with acyclic α,β-unsaturated ketones in the Michael sense as mentioned in this paper.
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A REGIO- AND STEREOSELECTIVE SYNTHESIS OF ALDOLIZED γ-DIKETONES VIA TIN(IV) BISENOLATES BY THE USE OF BIS(2-PYRIDINETHIOLATO)TIN(II)
TL;DR: Tin(IV) bisenolates of γ-diketones, generated regioselectively from α,β-unsaturated γ -dikets by the reaction with bis(2-pyridinethiolato)tin(II), react with aldehydes sterehetically to afford the corresponding aldolized γ dikets in good yields.
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Preparation of useful synthetic intermediates of Taxol analogs, cyclooctenone derivatives.
TL;DR: Stereoselective syntheses of omega-(alpha-bromoketo) octanals and nonanal with oxygenated functions and formation of the corresponding eight-membered carbocyclic aldols by subsequent samarium(II)-mediated cyclization are demonstrated.
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A Convenient Method for the Preparation of Ethers from Epoxides. Trityl Hexafluoroantimonate-Catalyzed Sequential Reactions, Rearrangement and Reductive Condensation, of Epoxides
TL;DR: In the presence of a catalytic amount of trityl hexafluoroantimonate, sequential reactions, rearrangement and reductive condensation, of epoxides proceed smoothly to give the corresponding ethers in fairly good yields.