다중혈관 관상동맥 환자에서 y-문합을 이용하여 양쪽 내흉동맥만을 사용한 우회술의 조기 성적

In 1978 it was discovered, largely through the work of Fleischmann, Van Duyne, Creighton, and their coworkers that molecules adsorbed on specially prepared silver surfaces produce a Raman spectrum that is at times a millionfold more intense than expected. This effect was dubbed surface-enhanced Raman scattering (SERS). Since then the effect has been demonstrated with many molecules and with a number of metals, including Cu, Ag, Au, Li, Na, K, In, Pt, and Rh. In addition, related phenomena such as surface-enhanced second-harmonic generation, four-wave mixing, absorption, and fluorescence have been observed. Although not all fine points of the enhancement mechanism have been clarified, the majority view is that the largest contributor to the intensity amplification results from the electric field enhancement that occurs in the vicinity of small, interacting metal particles that are illuminated with light resonant or near resonant with the localized surface-plasmon frequency of the metal structure. Small in this context is gauged in relation to the wavelength of light. The special preparations required to produce the effect, which include among other techniques electrochemical oxidation-reduction cycling, deposition of metal on very cold substrates, and the generation of metal-island films and colloids, is now understood to be necessary as a means of producing surfaces with appropriate electromagnetic resonances that may couple to electromagnetic fields either by generating rough films (as in the case of the former two examples) or by placing small metal particles in close proximity to one another (as in the case of the latter two). For molecules chemisorbed on SERS-active surface there exists a "chemical enhancement" in addition to the electromagnetic effect. Although difficult to measure accurately, the magnitude of this effect rarely exceeds a factor of 10 and is best thought to arise from the modification of the Raman polarizability tensor of the adsorbate resulting from the formation of a complex between the adsorbate and the metal. Rather than an enhancement mechanism, the chemical effect is more logically to be regarded as a change in the nature and identity of the adsorbate.

Surface-enhanced spectroscopy

Graphene, the single-atom-thick form of carbon, holds promise for many applications, notably in electronics where it can complement or be integrated with silicon-based devices. Intense efforts have been devoted to develop a key enabling device, a broadband, fast optical modulator with a small device footprint. Now Liu et al. demonstrate an exciting new possibility for graphene in the area of on-chip optical communication: a graphene-based optical modulator integrated with a silicon chip. This new device relies on the electrical tuning of the Fermi level of the graphene sheet, and achieves modulation of guided light at frequencies over 1 gigahertz, together with a broad operating spectrum. At just 25 square micrometres in area, it is one of the smallest of its type. Integrated optical modulators with high modulation speed, small footprint and large optical bandwidth are poised to be the enabling devices for on-chip optical interconnects1,2. Semiconductor modulators have therefore been heavily researched over the past few years. However, the device footprint of silicon-based modulators is of the order of millimetres, owing to its weak electro-optical properties3. Germanium and compound semiconductors, on the other hand, face the major challenge of integration with existing silicon electronics and photonics platforms4,5,6. Integrating silicon modulators with high-quality-factor optical resonators increases the modulation strength, but these devices suffer from intrinsic narrow bandwidth and require sophisticated optical design; they also have stringent fabrication requirements and limited temperature tolerances7. Finding a complementary metal-oxide-semiconductor (CMOS)-compatible material with adequate modulation speed and strength has therefore become a task of not only scientific interest, but also industrial importance. Here we experimentally demonstrate a broadband, high-speed, waveguide-integrated electroabsorption modulator based on monolayer graphene. By electrically tuning the Fermi level of the graphene sheet, we demonstrate modulation of the guided light at frequencies over 1 GHz, together with a broad operation spectrum that ranges from 1.35 to 1.6 µm under ambient conditions. The high modulation efficiency of graphene results in an active device area of merely 25 µm2, which is among the smallest to date. This graphene-based optical modulation mechanism, with combined advantages of compact footprint, low operation voltage and ultrafast modulation speed across a broad range of wavelengths, can enable novel architectures for on-chip optical communications.

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A graphene-based broadband optical modulator

We examine the current performance and future demands of interconnects to and on silicon chips. We compare electrical and optical interconnects and project the requirements for optoelectronic and optical devices if optics is to solve the major problems of interconnects for future high-performance silicon chips. Optics has potential benefits in interconnect density, energy, and timing. The necessity of low interconnect energy imposes low limits especially on the energy of the optical output devices, with a ~ 10 fJ/bit device energy target emerging. Some optical modulators and radical laser approaches may meet this requirement. Low (e.g., a few femtofarads or less) photodetector capacitance is important. Very compact wavelength splitters are essential for connecting the information to fibers. Dense waveguides are necessary on-chip or on boards for guided wave optical approaches, especially if very high clock rates or dense wavelength-division multiplexing (WDM) is to be avoided. Free-space optics potentially can handle the necessary bandwidths even without fast clocks or WDM. With such technology, however, optics may enable the continued scaling of interconnect capacity required by future chips.

Device Requirements for Optical Interconnects to Silicon Chips

Intracavity semiconductor saturable absorber mirrors (SESAM's) offer unique and exciting possibilities for passively pulsed solid-state laser systems, extending from Q-switched pulses in the nanosecond and picosecond regime to mode-locked pulses from 10's of picoseconds to sub-10 fs. This paper reviews the design requirements of SESAM's for stable pulse generation in both the mode-locked and Q-switched regime. The combination of device structure and material parameters for SESAM's provide sufficient design freedom to choose key parameters such as recovery time, saturation intensity, and saturation fluence, in a compact structure with low insertion loss. We have been able to demonstrate, for example, passive modelocking (with no Q-switching) using an intracavity saturable absorber in solid-state lasers with long upper state lifetimes (e.g., 1-/spl mu/m neodymium transitions), Kerr lens modelocking assisted with pulsewidths as short as 6.5 fs from a Ti:sapphire laser-the shortest pulses ever produced directly out of a laser without any external pulse compression, and passive Q-switching with pulses as short as 56 ps-the shortest pulses ever produced directly from a Q-switched solid-state laser. Diode-pumping of such lasers is leading to practical, real-world ultrafast sources, and we will review results on diode-pumped Cr:LiSAF, Nd:glass, Yb:YAG, Nd:YAG, Nd:YLF, Nd:LSB, and Nd:YVO/sub 4/.

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Semiconductor saturable absorber mirrors (SESAM's) for femtosecond to nanosecond pulse generation in solid-state lasers

We report experiments and theory on the effects of electric fields on the optical absorption near the band edge in GaAs/AlGaAs quantum-well structures. We find distinct physical effects for fields parallel and perpendicular to the quantum-well layers. In both cases, we observe large changes in the absorption near the exciton peaks. In the parallel-field case, the excitons broaden with field, disappearing at fields \ensuremath{\sim}${10}^{4}$ V/cm; this behavior is in qualitative agreement with previous theory and in order-of-magnitude agreement with direct theoretical calculations of field ionization rates reported in this paper. This behavior is also qualitatively similar to that seen with three-dimensional semiconductors. For the perpendicular-field case, we see shifts of the exciton peaks to lower energies by up to 2.5 times the zero-field binding energy with the excitons remaining resolved at up to \ensuremath{\sim}${10}^{5}$ V/cm: This behavior is qualitatively different from that of bulk semiconductors and is explained through a mechanism previously briefly described by us [D. A. B. Miller et al., Phys. Rev. Lett. 53, 2173 (1984)] called the quantum-confined Stark effect. In this mechanism the quantum confinement of carriers inhibits the exciton field ionization. To support this mechanism we present detailed calculations of the shift of exciton peaks including (i) exact solutions for single particles in infinite wells, (ii) tunneling resonance calculations for finite wells, and (iii) variational calculations of exciton binding energy in a field. We also calculate the tunneling lifetimes of particles in the wells to check the inhibition of field ionization. The calculations are performed using both the 85:15 split of band-gap discontinuity between conduction and valence bands and the recently proposed 57:43 split. Although the detailed calculations differ in the two cases, the overall shift of the exciton peaks is not very sensitive to split ratio. We find excellent agreement with experiment with no fitted parameters.

Electric field dependence of optical absorption near the band gap of quantum-well structures.

We present theory and extended experimental results for the large shift in optical absorption in GaAs-AlGaAs quantum well structures with electric field perpendicular to the layers. In contrast to the Stark effect on atoms or on excitons in bulk semiconductors, the exciton resonances remain resolved even for shifts much larger than the zero-field binding energy and fields g 50 times the classical ionization field. The model explains these results as a consequence of the quantum confinement of carriers.

Band-Edge Electroabsorption in Quantum Well Structures: The Quantum-Confined Stark Effect

We report extended experimental and theoretical results for the quantum well self-electrooptic effect devices. Four modes of operation are demonstrated: 1) optical bistability, 2) electrical bistability, 3) simultaneous optical and electronic self-oscillation, and 4) self-linearized modulation and optical level shifting. All of these can be observed at room-temperature with a CW laser diode as the light source. Bistability can be observed with 18 nW of incident power, or with 30 ns switching time at 1.6 mW with a reciprocal relation between switching power and speed. We also now report bistability with low electrical bias voltages (e.g., 2 V) using a constant current load. Negative resistance self-oscillation is observed with an inductive load; this imposes a self-modulation on the transmitted optical beam. With current bias, self-linearized modulation is obtained, with absorbed optical power linearly proportional to current. This is extended to demonstrate light-by-light modulation and incoherent-to-incoherent conversion using a separate photodiode. The nature of the optoelectronic feedback underlying the operation of the devices is discussed, and the physical mechanisms which give rise to the very low optical switching energy (∼4 fJ/ μm2) are discussed.

The quantum well self-electrooptic effect device: Optoelectronic bistability and oscillation, and self-linearized modulation

We report a new type of optoelectronic device, a self‐electro‐optic effect device (SEED), which uses the same GaAs/GaAlAs multiple quantum well material simultaneously as an optical detector and modulator. Using a series resistor and constant voltage bias supply the SEED shows optical bistabilty (OB) of the recently discovered type which relies on increasing absorption and requires no mirrors. OB is seen at room temperature from ∼850–860 nm, at powers as low as 670 nW or switching times as short as 400 ns (limited only by power restrictions) with ∼1‐nJ optical switching energy in a 600‐μm‐diam device. Total energies per unit area (∼18 fJ/μm2) are substantially lower than any previously reported for OB.We report a new type of optoelectronic device, a self‐electro‐optic effect device (SEED), which uses the same GaAs/GaAlAs multiple quantum well material simultaneously as an optical detector and modulator. Using a series resistor and constant voltage bias supply the SEED shows optical bistabilty (OB) of the recently discovered type which relies on increasing absorption and requires no mirrors. OB is seen at room temperature from ∼850–860 nm, at powers as low as 670 nW or switching times as short as 400 ns (limited only by power restrictions) with ∼1‐nJ optical switching energy in a 600‐μm‐diam device. Total energies per unit area (∼18 fJ/μm2) are substantially lower than any previously reported for OB.

Novel hybrid optically bistable switch: The quantum well self‐electro‐optic effect device

A new type of high‐speed optical modulator is proposed and demonstrated An electric field is applied perpendicular to GaAs/GaAlAs multiple quantum well layers using a ‘‘p‐i‐n’’ diode doping structure of 4‐μm total thickness The optical absorption edge, which is particularly abrupt because of exciton resonances, shifts to longer wavelengths with increasing field giving almost a factor of 2 reduction in transmission at 857 nm with an 8‐V reverse bias The shifts are ascribed to changes in carrier confinement energies in the wells The observed switching time of 28 ns is attributed to RC time constant and instrumental limitations only, and fundamental limits may be much faster

Thomas H. Wood

Papers

Electric field dependence of optical absorption near the band gap of quantum-well structures.

Band-Edge Electroabsorption in Quantum Well Structures: The Quantum-Confined Stark Effect

The quantum well self-electrooptic effect device: Optoelectronic bistability and oscillation, and self-linearized modulation

Novel hybrid optically bistable switch: The quantum well self‐electro‐optic effect device

High‐speed optical modulation with GaAs/GaAlAs quantum wells in a p‐i‐n diode structure