Elements Of X Ray Diffraction

This review article aims to provide an updated and comprehensive description of the development of the Electric Current Activated/assisted Sintering technique (ECAS) for the obtainment of dense materials including nanostructured ones. The use of ECAS for pure sintering purposes, when starting from already synthesized powders promoters, and to obtain the desired material by simultaneously performing synthesis and consolidation in one-step is reviewed. Specifically, more than a thousand papers published on this subject during the past decades are taken into account. The experimental procedures, formation mechanisms, characteristics, and functionality of a wide spectrum of dense materials fabricated by ECAS are presented. The influence of the most important operating parameters (i.e. current intensity, temperature, processing time, etc.) on product characteristics and process dynamics is reviewed for a large family of materials including ceramics, intermetallics, metal–ceramic and ceramic–ceramic composites. In this review, systems where synthesis and densification stages occur simultaneously, i.e. a fully dense product is formed immediately after reaction completion, as well as those ones for which a satisfactory densification degree is reached only by maintaining the application of the electric current once the full reaction conversion is obtained, are identified. In addition, emphasis is given to the obtainment of nanostructured dense materials due to their rapid progress and wide applications. Specifically, the effect of mechanical activation by ball milling of starting powders on ECAS process dynamics and product characteristics (i.e. density and microstructure) is analysed. The emerging theme from the large majority of the reviewed investigations is the comparison of ECAS over conventional methods including pressureless sintering, hot pressing, and others. Theoretical analysis pertaining to such technique is also proposed following the last results obtained on this topic.

Consolidation/synthesis of materials by electric current activated/assisted sintering

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Introduction To Electrodynamics

Wire Arc Additive Manufacturing (WAAM) is attracting significant attention in industry and academia due to its ability to capture the benefits of additive manufacturing for production of large components of medium geometric complexity. Uniquely, WAAM combines the use of wire and electric arc as a fusion source to build components in a layer-by-layer approach, both of which can offer significant cost savings compared to powder and alternative fusion sources, such as laser and electron beam, respectively. Meanwhile, a high deposition rate, key for producing such components, is provided, whilst also allowing significant material savings compared to conventional manufacturing processes. However, high quality production in a wide range of materials is limited by the elevated levels of heat input which causes a number of materials processing challenges in WAAM. The materials processing challenges are fully identified in this paper to include the development of high residual stresses, undesirable microstructures, and solute segregation and phase transformations at solidification. The thermal profile during the build poses another challenge leading to heterogeneous and anisotropic material properties. This paper outlines how the materials processing challenges may be addressed in WAAM by implementation of quality improving ancillary processes. The primary WAAM process selections and ancillary processes are classified by the authors and a comprehensive review of their application conducted. Strategies by which the ancillary processes can enhance the quality of WAAM parts are presented. The efficacy and suitability of these strategies for versatile and cost effective WAAM production are discussed and a future vision of WAAM process developments provided.

https://purehost.bath.ac.uk/ws/files/183236429/StrategiesAndProcessesForHighQualityWireArcAdditiveManufacturing_Manuscript.pdf

Invited review article: Strategies and processes for high quality wire arc additive manufacturing

Functionally graded material of 304L stainless steel and inconel 625 fabricated by directed energy deposition: Characterization and thermodynamic modeling

Improvement of mechanical properties of ferritic stainless steel weld metal by ultrasonic vibration

Quantitative information on the parameters associated with self-propelled objects would enhance the potential of this research field; for example, finding a realistic way to develop a functional self-propelled object and quantitative understanding of the mechanism of self-motion. We therefore estimated five main parameters, including the driving force, of a camphor boat as a simple self-propelled object that spontaneously moves on water due to difference in surface tension. The experimental results and mathematical model indicated that the camphor boat generated a driving force of 4.2 μN, which corresponds to a difference in surface tension of 1.1 mN m–1. The methods used in this study are not restricted to evaluate the parameters of self-motion of a camphor boat, but can be applied to other self-propelled objects driven by difference in surface tension. Thus, our investigation provides a novel method to quantitatively estimate the parameters for self-propelled objects driven by the interfacial tension di...

https://pubs.acs.org/doi/pdf/10.1021/la501628d

Quantitative estimation of the parameters for self-motion driven by difference in surface tension.

Foil aluminizing of steel, wherein Al diffuses to the base steel material by diffusion treatment after hot pressing of the aluminum foil at a lower temperature than the melting point, was performed in this study. Alloy layers formed by diffusion at temperatures ranging from 700 to 1000 °C were investigated, and their features were compared with those of hot-dip aluminized steel. In hot-dip aluminizing, an intermediate Fe 2 Al 5 layer was formed between the aluminum layer and the base steel during aluminum coating before the diffusion treatment. In contrast, the coating layer of the foil-aluminized steel specimen after diffusion bonding of the aluminum foil consisted only of the Al layer. An Fe 2 Al 5 layer, an FeAl layer and an Al diffused layer were formed in both the aluminized specimens subsequent to the diffusion treatment. The numbers of voids formed in the Fe 2 Al 5 layer and at the FeAl/Al diffused layer interface of the foil-aluminized specimens are smaller than those for hot-dip aluminizing. Moreover, the FeAl and Al diffused layers are formed with a greater thickness in the foil-aluminized steel under identical diffusion conditions. The Al concentration in hot-dip aluminized steel decreased in stages from the surface to the base steel, whereas, in the foil-aluminized steel, it decreased gradually. The Fe 2 Al 5 /base steel interface in the foil-aluminized steel was thus indistinct, and cross-sectional hardness also decreased gradually.

Features of intermetallic compounds in aluminized steels formed using aluminum foil

G phase an intermetallic silicide has been observed in martensite of precipitation hardened stainless steels and in the ferrite of dual (austenite and ferrite) phase stainless steels. In both cases, before G-phase precipitates, the matrix composition changes due to spinodal decomposition and solute partitioning between ferrite and austenite. Thus in the present study, single bcc phase and high Ni content stainless steel, was selected to study G-phase precipitation expecting elimination of the interference from spinodal decomposition and solute partitioning. Fe–18Cr–8Ni (SUS304) austenitic stainless steel samples were deformed at room temperature by high pressure torsion to obtain 100% volume fraction of deformation induced martensite (α′). HPT deformation was chosen due to its ability to induce high strength by grain refinement and also attain 100% α′ at room temperature. After annealing at 400 °C for 500 h, G-phase precipitation was observed in the fully martensitic matrix without spinodal decomposition. Crystallographic analysis of annealed samples using high resolution transmission electron microscopy (HRTEM) and energy dispersive spectroscopy (EDS) detected a Mn–Ni–Si rich G-phase with fcc crystal structure with lattice parameter of 1.16 nm. The value of lattice parameter corresponds well with previously reported values. Chemical analysis by atom probe tomography (APT) showed G-phase of composition Mn 21 Ni 50 Si 24 Fe 4 Cr. Tensile tests showed that G-phase precipitation leads to the embrittlement in the ferrite phase. G-phase precipitation in a single bcc phase specimen without prior spinodal decomposition and embrittlement solely due to G-phase is reported for the first time.

G-phase precipitation in austenitic stainless steel deformed by high pressure torsion

Coating of aluminide on a TiAl-based alloy (49.1 at.% Al) was carried out by thermal spraying pure aluminum and subsequent diffusion treatment at 1100 °C. The growth of a Ti–Al intermetallic layer in the coating layers during diffusion treatment for 120–1800 s as well as the oxidation resistance of the aluminized TiAl-based alloy was investigated. The outermost surface layer was comprised of Al-rich intermetallic TiAl 3 and contained pores. In contrast, an Al concentration gradient layer consisting of Ti 2 Al 5 , TiAl 2 , and Al-rich TiAl containing 55 at.% Al was formed between the outermost layer and the substrate. The thickness of the outermost layer decreased with increasing diffusion time, while the thickness of the intermediate layer grew to approximately 30 μm. In addition, the coating/substrate interface changed from a wavy to a linear form with the growth of the intermediate layer. The aluminized coating, at all diffusion times, showed good oxidation resistance in cyclic oxidation tests at 900 °C in air.

Tomohiro Sasaki

Papers

Improvement of mechanical properties of ferritic stainless steel weld metal by ultrasonic vibration

Quantitative estimation of the parameters for self-motion driven by difference in surface tension.

Features of intermetallic compounds in aluminized steels formed using aluminum foil

G-phase precipitation in austenitic stainless steel deformed by high pressure torsion

Aluminizing of TiAl-based alloy using thermal spray coating